石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (8): 154-163.

• 综述 • 上一篇    下一篇

工业氧化铝载体挤条成型工艺与数学建模研究进展

侯冉冉,刘锋,李会峰,韩伟,刘清河   

  1. 中石化石油化工科学研究院有限公司
  • 收稿日期:2025-12-22 修回日期:2026-03-19 出版日期:2026-08-12 发布日期:2026-07-23
  • 通讯作者: 刘锋 E-mail:liuf.ripp@sinopec.com

RESEARCH PROGRESS ON EXTRUSION PROCESS AND MATHEMATICAL MODELING OF INDUSTRIAL ALUMINA SUPPORTS

  • Received:2025-12-22 Revised:2026-03-19 Online:2026-08-12 Published:2026-07-23

摘要: 氧化铝是最常用的催化剂载体,作为催化剂的重要组成部分,其性质直接影响催化剂的反应性能。挤条成型是工业制备氧化铝载体的常用方法,其流程包含原料预处理、成型加工、热处理等步骤,各步骤的工艺参数均会对载体性质产生重要影响。综述了原料拟薄水铝石的物相结构对载体性质的影响,梳理了挤出成型过程中各工艺条件对载体机械强度和孔结构等性质的调控机理,在此基础上探讨了数学模型在解析颗粒混合行为、优化干燥与焙烧过程、建立工艺-结构-性能关联中的关键作用。通过构建数学模型建立各操作参数与载体结构的可视化关联,在保证载体生产过程平稳进行的同时进一步提高载体质量,为实现载体生产过程从“经验调控”转变为“数据驱动”的发展提供参考。

关键词: 氧化铝载体, 拟薄水铝石, 数学模型, 热处理, 挤条成型

Abstract: Alumina is the most commonly used catalyst support. As a crucial component of catalysts, its properties directly influence the reaction performance of the catalyst.The common extrusion process for preparing technical alumina supports involves multiple steps including raw material pretreatment, shaping, and heat treatment. The process parameters at each step significantly affect the properties of the final support. This review summarizes the influence of the phase structure of the precursor pseudo-boehmite on support properties, and systematically analyzes the regulatory mechanisms of various process conditions on support strength and pore structure during extrusion. On this basis, the key role of mathematical models in analyzing particle mixing behavior, optimizing drying and calcination processes, and establishing process-structure-performance relationships is discussed. By constructing mathematical model to establish a visual correlation between operational parameters and support,table production can be ensured while further improving support quality, providing a reference for achieving the transformation of the support production process from "empirical regulation" to "data-driven" development.

Key words: alumina support, pseudo boehmite, mathematical model, heat treatment, extrusion molding