石油炼制与化工 ›› 2026, Vol. 57 ›› Issue (8): 140-153.

• 综述 • 上一篇    下一篇

生物质催化热解生产轻质芳烃催化剂的研究进展

李成林1,朱根权1,李想1,曹东学2   

  1. 1. 中石化石油化工科学研究院有限公司
    2. 中国石油化工股份有限公司炼油事业部
  • 收稿日期:2026-02-11 修回日期:2026-03-26 出版日期:2026-08-12 发布日期:2026-07-23
  • 通讯作者: 朱根权 E-mail:zhugq.ripp@sinopec.com
  • 基金资助:
    国家重点研发计划;中国石油化工股份有限公司项目基金

RESEARCH PROGRESS IN CATALYSTS FOR CATALYTIC PYROLYSIS OF BIOMASS TO PRODUCE LIGHT AROMATIC HYDROCARBONS

  • Received:2026-02-11 Revised:2026-03-26 Online:2026-08-12 Published:2026-07-23

摘要: 生物质作为含碳可再生资源,可通过催化热解方式制备轻质芳烃苯、甲苯、二甲苯(BTXs)。但生物质生成的BTXs的产率较低,且生物质含氧量高、矿物杂质多,所以仍需要对该过程进行深入研究,以提高生物质生产BTXs的效率和效益。综述了生物质原料、催化热解工艺和机理,并重点探讨了多级孔分子筛、金属氧化物和复合催化剂在提高BTXs产率和生物油质量方面的作用。碱性金属氧化物可以降低生物油中含氧化合物的含量,并且与分子筛催化剂组成的复合催化剂可有效提升BTXs产率,展现出较好的应用前景。总结了生物质原料和催化剂对BTXs产率及选择性的影响,最后对负载金属氧化物的多级孔分子筛催化剂在生物质催化热解领域的应用前景进行了展望。

关键词: 生物质, 热解, 催化剂, 催化热解, 木质纤维素类生物质, 生物油

Abstract: Biomass, as a carbon-containing renewable resource, can be converted into light aromatic hydrocarbons(BTXs) through catalytic pyrolysis. Nevertheless, the yield of BTXs produced from biomass is relatively low. Meanwhile, the high oxygen content and abundant mineral impurities in biomass make it essential to conduct in-depth research on this process, so as to improve the efficiency and economic benefits of BTXs production from biomass. This paper reviews biomass feedstocks, catalytic pyrolysis processes and corresponding mechanisms, and emphatically discusses the roles of hierarchical zeolites, metal oxides,and composite catalysts in increasing BTXs yield and upgrading bio-oil quality. Basic metal oxides can reduce the content of oxygenated compounds in bio-oil. Furthermore, composite catalysts constructed by basic metal oxides and zeolite catalysts can effectively enhance BTXs yield, showing favorable application prospects. The effects of biomass feedstocks and catalysts on the yield and selectivity of BTXs are summarized. Finally, the application prospects of hierarchical zeolite catalysts loaded with metal oxides in the field of biomass catalytic pyrolysis are prospected.

Key words: biomass, pyrolysis, catalyst, catalytic pyrolysis, lignocellulosic biomass, bio-oil