CHARACTERIZATION AND CONSTRUCTION METHODS OF STRONG METAL-SUPPORT INTERACTION AND ITS APPLICATION PROGRESS

Abstract

Abstract: Strong metal-support interaction (SMSI) occupies a core position in catalysis research and plays a crucial role in modulating the performance of metal-supported catalysts. By changing the geometric structuresand electronic structures of the active metal components in supported catalysts, the SMSI effect can enhance catalytic activity and selectivity for target products, as well as improve catalyst stability.A detailed discussion on the characterization techniques, typical features, construction strategies, and applicable scenarios of the SMSI effect was presented. The progress of SMSI in the fields of energy conversion, environmental protection, and fine chemical synthesis were reviewed, and its catalytic mechanisms was explored. In the future, more efficient characterization techniques need to be developed to deeply reveal the formation mechanism of SMSI effect. In addition, the application areas of SMSI effect should be expanded to meet the catalysis needs of different industrial scenarios and environments.

Key words: strong metal-support interaction, electron transfer, cladding structure, reversibility, adsorbate induction method, atomic layer deposition method

References

[1] Li S.，Xu Y.，Chen Y.，et al. Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction[J]. Angewandte Chemie International Edition，2017，56(36)：10761-10765
[2] van Deelen Tom W.，Hernández Mejía Carlos，de Jong Krijn P. Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity[J]. Nature Catalysis，2019，2(11)：955-970
[3] Otor Hope O.，Steiner Joshua B.，García-Sancho Cristina，et al. Encapsulation Methods for Control of Catalyst Deactivation: A Review[J]. ACS Catalysis，2020，10(14)：7630-7656
[4] Tauster S, J.，Fung S.C.，Garten R. L. Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide[J]. Journal of the American Chemical Society，1978，100(1)：170–175
[5] R. BURCH，A.R. FLAMBARD. Strong Metal-Support Interactions in Nickel/Titania Catalysts: The Importance of interfacial Phenomena[J]. Journal of Catalysis，1982，78：389-405
[6] E. Golunski Stanislaw，A. Hatcher Helen，Rajaram Raj R.，et al. Origins of low-temperature three-way activity in Pt/CeO2[J]. Applied Catalysis B: Environmental，1995，5：367-376
[7] Wang Liang，Zhang Jian，Zhu Yihan，et al. Strong Metal–Support Interactions Achieved by Hydroxide-to-Oxide Support Transformation for Preparation of Sinter-Resistant Gold Nanoparticle Catalysts[J]. ACS Catalysis，2017，7(11)：7461-7465
[8] Liu X.，Liu M. H.，Luo Y. C.，et al. Strong metal-support interactions between gold nanoparticles and ZnO nanorods in CO oxidation[J]. Journal of the American Chemical Society，2012，134(24)：10251-10258
[9] Matsubu J. C.，Zhang S.，DeRita L.，et al. Adsorbate-mediated strong metal-support interactions in oxide-supported Rh catalysts[J]. Nature Chemistry，2017，9(2)：120-127
[10] A. Horsley J. A Molecular Orbital Study of Strong Metal-Support Interaction between Platinum and Titanium Dioxide[J]. Journal of the American Chemical Society，1979，101(11)：2870-2874
[11] 唐胜，熊国兴，蔡海林，et al. Pt-TiO2, Pt-Ti2O3与Pt-TiO共溅射薄膜模型催化剂上的金属-担体间相互作用I. TEM与HEED考察[J]. 催化学报，1987，8(3)：225-233
[12] 陈怡萱，陈燕馨. 高温氢处理后Pt-TiO2催化剂的表面重组[J]. 催化学报，1987，3(8)：310-314
[13] Qiang Fu，Thomas Wagner，Sven Olliges，et al. Metal-Oxide Interfacial Reactions: Encapsulation of Pd on TiO2(110)[J]. The Journal of Physical Chemistry B，2005，109(2)：944-951
[14] Zhang S.，Plessow P. N.，Willis J. J.，et al. Dynamical Observation and Detailed Description of Catalysts under Strong Metal-Support Interaction[J]. Nano Letters，2016，16(7)：4528-4534
[15] Tang Hailian，Su Yang，Zhang Bingsen，et al. Classical strong metal–support interactions between gold nanoparticles and titanium dioxide[J]. Science Advances，2017，3(10)
[16] Tang H.，Wei J.，Liu F.，et al. Strong Metal-Support Interactions between Gold Nanoparticles and Nonoxides[J]. Journal of the American Chemical Society，2016，138(1)：56-59
[17] SINGH ANAND K.，PANDE NUTAN K.，BELL ALEXIS T. Electron Microscopy Study of the Interactions of Rhodium with Titania[J]. Journal of Catalysis，1985，94：422-435
[18] BRAUNSCHWEIG EHRICH J.，LOGAN A. DAVID，DATYE ABHAYA K.，et al. Reversibility of Strong Metal-Support Interactions on Rh/TiO2[J]. Journal of Catalysis，1989，118：227-237
[19] Zhang Yaru，Yan Wenjie，Qi Haifeng，et al. Strong Metal–Support Interaction of Ru on TiO2 Derived from the Co-Reduction Mechanism of RuxTi1–xO2 Interphase[J]. ACS Catalysis，2022，12(3)：1697-1705
[20] Dong J.，Fu Q.，Li H.，et al. Reaction-Induced Strong Metal-Support Interactions between Metals and Inert Boron Nitride Nanosheets[J]. Journal of the American Chemical Society，2020，142(40)：17167-17174
[21] Zhang J.，Zhu D.，Yan J.，et al. Strong metal-support interactions induced by an ultrafast laser[J]. Nature Communications，2021，12(1)：6665
[22] Xin H.，Lin L.，Li R.，et al. Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal-Support Interactions[J]. Journal of the American Chemical Society，2022，144(11)：4874-4882
[23] Pu Tiancheng，Setiawan Adhika，Mosevitzky Lis Bar，et al. Nature and Reactivity of Oxygen Species on/in Silver Catalysts during Ethylene Oxidation[J]. ACS Catalysis，2022，12(8)：4375-4381
[24] Zhu M.，Tian P.，Kurtz R.，et al. Strong Metal-Support Interactions between Copper and Iron Oxide during the High-Temperature Water-Gas Shift Reaction[J]. Angewandte Chemie International Edition，2019，58(27)：9083-9087
[25] Zhang Y.，Yang X.，Yang X.，et al. Tuning reactivity of Fischer-Tropsch synthesis by regulating TiOx overlayer over Ru/TiO2 nanocatalysts[J]. Nature Communications，2020，11(1)：3185
[26] Tauster S.J.，Fung S.C. Strong Metal-Support Interactions: Occurrence among the Binary Oxides of Groups llA-VB[J]. Journal of Catalysis，1978，55：29-35
[27] Liu S.，Xu W.，Niu Y.，et al. Ultrastable Au nanoparticles on titania through an encapsulation strategy under oxidative atmosphere[J]. Nat Commun，2019，10(1)：5790
[28] Wang Hai，Wang Liang，Lin Dong，et al. Strong metal–support interactions on gold nanoparticle catalysts achieved through Le Chatelier’s principle[J]. Nature Catalysis，2021，4(5)：418-424
[29] Zhang Jian，Wang Hai，Wang Liang，et al. Wet-Chemistry Strong Metal-Support Interactions in Titania Supported Au Catalysts[J]. Journal of the American Chemical Society，2019，141(7)：2975–2983
[30] Chen Hao，Yang Zhenzhen，Wang Xiang，et al. Photoinduced Strong Metal–Support Interaction for Enhanced Catalysis[J]. Journal of the American Chemical Society，2021，143(23)：8521-8526
[31] McNeary W. Wilson，Tacey Sean A.，Lahti Gabriella D.，et al. Atomic Layer Deposition with TiO2 for Enhanced Reactivity and Stability of Aromatic Hydrogenation Catalysts[J]. ACS Catalysis，2021，11(14)：8538-8549
[32] Reina Alfonso，Son Hyungbin，Jiao Liying，et al. Transferring and Identification of Single- and Few-Layer Graphene on Arbitrary Substrates[J]. The Journal of Physical Chemistry C，2008，112(46)：17741–17744
[33] Zhang Y.，Liu J. X.，Qian K.，et al. Structure Sensitivity of Au-TiO2 Strong Metal-Support Interactions[J]. Angewandte Chemie International Edition，2021，60(21)：12074-12081
[34] Fujita T.，Guan P.，McKenna K.，et al. Atomic origins of the high catalytic activity of nanoporous gold[J]. Nature Materials，2012，11(9)：775-780
[35] Zhang Chenchen，Wang Letian，Chen Yuzhen，et al. Shifting CO2 hydrogenation from producing CO to CH3OH by engineering defect structures of Cu/ZrO2 and Cu/ZnO catalysts[J]. Chemical Engineering Journal，2023，475
[36] Zhang Chenchen，Wang Letian，Etim Ubong Jerome，et al. Oxygen vacancies in Cu/TiO2 boost strong metal-support interaction and CO2 hydrogenation to methanol[J]. Journal of Catalysis，2022，413：284-296
[37] Deng L.，Miura H.，Shishido T.，et al. Strong metal-support interaction between Pt and SiO2 following high-temperature reduction: a catalytic interface for propane dehydrogenation[J]. Chem Commun，2017，53(51)：6937-6940
[38] Shao Jingling，Li Chao，Fei Zhaoyang，et al. MOFs-derived Ni@ZrO2 catalyst for dry reforming of methane: Tunable metal-support interaction[J]. Molecular Catalysis，2024，558
[39] Liu Yan，Li Lei，Zhang Junfeng，et al. Fabrication of highly active and durable Co/Al2O3 Fischer–Tropsch catalysts via coordination-assisted impregnation strategy[J]. Fuel，2024，375
[40] Wang Yi，Li Zhaohong，Zheng Xingqun，et al. Renovating phase constitution and construction of Pt nanocubes for electrocatalysis of methanol oxidation via a solvothermal-induced strong metal-support interaction[J]. Applied Catalysis B: Environmental，2023，325
[41] Li Jian，Lin Yaping，Pan Xiulian，et al. Enhanced CO2 Methanation Activity of Ni/Anatase Catalyst by Tuning Strong Metal–Support Interactions[J]. ACS Catalysis，2019，9(7)：6342-6348
[42] Cai Zhongjie，Dai Jiajun，Li Wen，et al. Pd Supported on MIL-68(In)-Derived In2O3 Nanotubes as Superior Catalysts to Boost CO2 Hydrogenation to Methanol[J]. ACS Catalysis，2020，10(22)：13275-13289
[43] Lu Zhenpu，Sun Guodong，Chen Sai，et al. Modulation of metal–support interactions in Pt–TiOx synergistic catalysts for propane dehydrogenation[J]. Chemical Engineering Science，2024，297
[44] Ma Jun，Liu Tianyang，Chen Guangyu，et al. Tuning the selectivity of photothermal CO2 hydrogenation through photo-induced interaction between Ni nanoparticles and TiO2[J]. Applied Catalysis B: Environmental，2024，344
[45] Lee Jechan，Burt Samuel P.，Carrero Carlos A.，et al. Stabilizing cobalt catalysts for aqueous-phase reactions by strong metal-support interaction[J]. Journal of Catalysis，2015，330：19-27