石油炼制与化工

• 催化剂 • 上一篇    下一篇

β分子筛在加氢裂化反应中催化性能特点研究

杜艳泽1,乔楠森2,王凤来1,关明华1   

  1. 1. 抚顺石油化工研究院
    2. 中国石油吉林石化公司炼油厂
  • 收稿日期:2011-01-04 修回日期:1900-01-01 出版日期:2011-08-12 发布日期:2011-08-12
  • 通讯作者: 杜艳泽

STUDY ON THE CATALYTIC PERFORMANCE OF ZEOLITE BETA IN HYDROCRACKING

  • Received:2011-01-04 Revised:1900-01-01 Online:2011-08-12 Published:2011-08-12

摘要: 对β分子筛结构特点进行介绍,将β分子筛与Y型分子筛和无定形硅铝的加氢裂化性能进行试验对比,在相同工艺条件下,与Y型分子筛和无定形硅铝等酸性组分相比,β分子筛加氢裂化催化剂中间馏分油选择性提高2.0百分点以上,柴油凝点降低4~12℃。β分子筛在加氢裂化反应中表现出异构性能好、裂化活性高、中间馏分油选择性好、产品质量好、抗氮能力强等特点,具有良好的催化活性、中间馏分油选择性及产品低温流动性,可应用于最大量生产中间馏分油加氢裂化催化剂。

关键词: β 分子筛, 加氢裂化, 催化剂, 中油选择性

Abstract: A brief introduction of the characteristics of zeolite β structure was presented. The hydrocracking performance of catalyst containing zeolite β was studied on a 200 mL hydrocracking device, and compared with catalyst containing zeolite Y and amorphous silica-alumina catalyst. Results show that under the same process conditions, catalysts containing zeolite β exhibit better catalytic performance during hydrocracking than the others: the selectivity of middle distillates is more than two percentage points higher, the setting point of diesel fractions is 4-12℃ lower, as well as good isomerization property, high cracking activity and strong nitrogen tolerance, which indicates that hydrocracking catalyst containing zeolite β can be used for maximizing middle distillates production.

Key words: β Zeolite, Hydrocracking, Catalyst, Middle distillates selectivity