石油炼制与化工 ›› 2012, Vol. 43 ›› Issue (10): 64-68.

• 加工工艺 • 上一篇    下一篇

降低催化裂化烟气中SO2排放的硫转移剂的工业试验

张强1,杨文慧1,李春义1,王瑜2   

  1. 1. 中国石油大学(华东)重质油国家重点实验室
      2. 中国石化胜利油田有限公司胜利石化总厂
  • 收稿日期:2012-02-10 修回日期:2012-04-27 出版日期:2012-10-12 发布日期:2012-09-26
  • 通讯作者: 李春义 E-mail:chyli@upc.edu.cn
  • 基金资助:

    中央高校基本科研业务费专项资金资助

COMMERCIAL TRIAL OF SULFUR TRANSFER ADDITIVE FOR REDUCING SULFUR DIOXIDE EMISSIONS IN FCC FLUE GAS

  • Received:2012-02-10 Revised:2012-04-27 Online:2012-10-12 Published:2012-09-26

摘要: 介绍中国石油大学(华东)开发、青岛神飞化工科技有限公司生产的无毒催化裂化烟气硫转移剂SFTS-1在中国石化胜利油田有限公司胜利石化总厂进行工业试验的情况。结果表明,在原料油性质和装置操作条件基本不变的前提下,添加4%的硫转移剂,稳定加剂6天后,再生烟气中二氧化硫的质量浓度从1 300 mg/m3降至245 mg/m3,脱硫率保持在80%以上;停止加剂11天后,脱硫率仍能达到69%。同时,硫转移剂对催化裂化产物分布和产品的性质没有不利的影响。

Abstract: The commercial trial of a nontoxic sulfur transfer additive SFTS-1 for reducing sulfur dioxide emissions in FCC flue gas developed by China University of Petroleum (East China) was carried out at Petrochemical Plant of Shengli Oilfield Co. Ltd. SINOPEC and it was introduced in this paper. Trial results showed that compared with base case under similar feedstock properties and operation parameters, when said additive occupied 4% of the catalyst inventory and stabilized at this level for 6 d, the SO2 content in regeneration flue gas dropped from 1 300 mg/m3 to 245 mg/m3, keeping a sulfur removal rate of above 80%; then without adding additive for 11 d, the sulfur removal rate still could be remained at 69%. At the same time, no significant negative effect on product distributions and product properties was observed during the trial.