石油炼制与化工 ›› 2012, Vol. 43 ›› Issue (4): 15-20.

• 催化剂 • 上一篇    下一篇

低积炭速率连续重整催化剂研发及工业应用

马爱增1,潘锦程1,杨森年1,汪莹2   

  1. 1. 中国石化石油化工科学研究院
    2. 湖南建长石化股份有限公司
  • 收稿日期:2011-10-14 修回日期:2011-10-31 出版日期:2012-04-12 发布日期:2012-03-29
  • 通讯作者: 马爱增 E-mail:maaizeng.ripp@sinopec.com

DEVELOPMENT AND COMMERCIAL APPLICATION OF CCR REFORMING CATALYSTS HAVING LOW COKE DEPOSITION RATE

  • Received:2011-10-14 Revised:2011-10-31 Online:2012-04-12 Published:2012-03-29
  • Contact: Aizeng Ma E-mail:maaizeng.ripp@sinopec.com

摘要: 中国石化石油化工科学研究院通过引入新助剂及采用新的制备技术,调控催化剂的活性中心,成功开发了低积炭速率、高选择性的PS-Ⅵ型连续重整催化剂,催化剂积炭量比参比催化剂PS-V下降了21%,液体收率和芳烃产率均进一步提高。在此基础上,通过进一步优化助剂与Pt中心的相互作用,改进制备工艺流程,实现了对金属中心微观结构的调变及两种Pt中心比例的调控,开发了PS-Ⅶ型催化剂,解决了高铂型催化剂高积炭的难题,并实现工业化。工业运转结果表明,与已有技术相比,PS-Ⅶ型催化剂的积炭量下降了36%,液体、芳烃和氢气产率均有大幅度提高。

关键词: 催化重整, 催化剂, 汽油 , 芳烃 , 积炭

Abstract: By means of adopting new promoters and preparation procedures to adjust the acidic and metallic active centers of CCR catalyst, a low coke deposition and high selective PS-VI catalyst was developed by Research Institute of Petroleum Processing. Compared with the previous PS-V catalyst, PS-VI catalyst showed a 21% decrease in coke deposition, yet its yields of reformate and aromatics increased. Based on these experiences, by optimizing the interaction between promoters and Pt centers to further adjust the microstructure and the ratio of two kinds of Pt centers, PS-VII catalyst was obtained and commercialized. The application results showed that the coke deposition of PS-VII catalyst decreased by 36% as compared with reference catalyst, at the same time, the yields of reformate, aromatics and hydrogen increased significantly.

Key words: catalytic reforming, catalyst, gasoline , aromatic hydrocarbon , coke deposit

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