石油炼制与化工 ›› 2012, Vol. 43 ›› Issue (4): 34-37.

• 基础研究 • 上一篇    下一篇

增加润滑油馏分芳烃含量的脱氢反应研究

臧明虹,蔡烈奎,朱路新,郑海琼   

  1. 中国石油克拉玛依石化分公司炼油化工研究院
  • 收稿日期:2011-07-06 修回日期:2011-10-27 出版日期:2012-04-12 发布日期:2012-03-29
  • 通讯作者: 臧明虹 E-mail:ypszangminghong@petrochina.com.cn

PRELIMINARY STUDY ON DEHYDROGENATION OF LUBE FRACTION TO FORM AROMATIC HYDROCARBONS

  • Received:2011-07-06 Revised:2011-10-27 Online:2012-04-12 Published:2012-03-29
  • Contact: Minghong Zang E-mail:ypszangminghong@petrochina.com.cn

摘要: 考察了润滑油馏分在一种负载型贵金属催化剂作用下,在不同反应温度和反应压力下,生成芳烃的变化趋势。结果表明:润滑油馏分的脱氢反应,在6 MPa的反应压力下,随着反应温度的变化,存在热力学平衡点,超过此温度点,有利于芳烃生成;氢气分压对润滑油脱氢反应影响很大,在360 ℃的反应温度下,随着反应压力的变化,存在热力学平衡点,反应压力低于10 MPa,有利于芳烃生成。在高温低压下,反应后大量的褐色物质吸附在催化剂上,清洗困难,不易脱附。

关键词: 脱氢反应 , 贵金属, 催化剂, 润滑油 , 芳烃

Abstract: The aromatics formation trend of lube fraction under various reaction temperatures and hydrogen partial pressures was investigated over a supported noble metal catalyst. Test results show that with a reaction pressure of 6 MPa, the dehydrogenation reaction rate of lube fraction changes with the reaction temperature, and there is a thermodynamic equilibrium point, when the temperature exceeds this point, the reactions of aromatics formation are favored; the same to reaction pressure, under a reaction temperature of 360℃, when the reaction pressure is below the thermodynamic equilibrium point of 10 MPa, the reaction rates of aromatics formation speed up. Under high temperature and low pressure, some brown substances are adsorbed on the catalyst, and it is not easy to be cleaned or to be desorbed.

Key words: dehydrogenation , noble metal, catalyst, Lubricating oil , aromatics

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