石油炼制与化工 ›› 2012, Vol. 43 ›› Issue (5): 19-23.

• 加工工艺 • 上一篇    下一篇

两段串联浆态床费-托合成新工艺

石玉林1,2,王洪学1,谢晶1,吴秀章1   

  1. 1. 中国神华煤制油化工有限公司
      2. 北京低碳清洁能源研究所
  • 收稿日期:2011-09-08 修回日期:2011-10-28 出版日期:2012-05-12 发布日期:2012-04-28
  • 通讯作者: 石玉林 E-mail:wanghongxue@csclc.com
  • 基金资助:

    国家高技术研究发展计划(863计划)“煤合成燃油(CTL)组分及汽车匹配技术研究与开发”项目资助

A NEW TWO-STAGE IN SERIES PROCESS OF SLURRY BED FISCHER-TROPSCH SYNTHESIS

  • Received:2011-09-08 Revised:2011-10-28 Online:2012-05-12 Published:2012-04-28

摘要: 采用中试装置对具有自主知识产权的两段串联费-托合成工艺以及传统的单段浆态床费-托合成工艺进行了模拟试验。对装置试验结果进行了数据处理和两种工艺的性能比较。在相同合成气处理量或相同装置产油量条件下,与单段浆态床费-托合成工艺比较,两段串联浆态床费-托合成工艺所需的催化剂量少20%以上,反应器单位体积有效利用率高;降低气体循环总量约60%,降低了能耗和操作费用;装置集成度高,可以减少部分设备,减少初期投资成本。

Abstract: Simulation tests of a patent two-stage in series process and conventional single-stage process for Fischer-Tropsch synthesis were carried out on a 10 L(oil)/h pilot plant slurry bed reactor system continuously, using a commercial precipitation iron catalyst. The test results show that as compared with single-stage process under the same processing capacity or oil yield, the required catalyst of this new process is more than 20% less, the processing capacity of per unit volume reactor is much higher and a reduction of about 60% total circulating gas is observed, thus the energy consumption and operation cost are lower. This unit is more integrated and its initial investment is also lower since a few equipments, such as a recycle gas compressor can be omitted.