石油炼制与化工 ›› 2012, Vol. 43 ›› Issue (6): 71-75.

• 油品与添加剂 • 上一篇    下一篇

脂肪酸甲酯型含氮硼酸酯的合成及摩擦学性能研究

李为民,任朋飞,段伟娜   

  1. 常州大学石油化工学院
  • 收稿日期:2011-10-28 修回日期:2011-11-18 出版日期:2012-06-12 发布日期:2012-05-31
  • 通讯作者: 李为民 E-mail:Liweimin@cczu.edu.cn
  • 基金资助:

    江苏省科技厅国际合作项目;江苏省科技厅工程技术中心建设项目

SYNTHESIS AND TRIBOLOGICAL BEHAVIOR OF A NITROGEN-CONTAINING BORIC ACID ESTER FROM FATTY ACID METHYL ESTER

  • Received:2011-10-28 Revised:2011-11-18 Online:2012-06-12 Published:2012-05-31

摘要: 以脂肪酸甲酯为原料合成了一种新型含氮硼酸酯添加剂。通过红外对所合成添加剂进行了表征,采用四球摩擦试验仪考察了其在不同基础油中的摩擦学性能,同时考察了摩擦时间、载荷对菜籽油磨斑直径(WSD)的影响,并用扫描电子显微镜(SEM)和能谱仪(EDS)分析了含氮硼酸酯添加剂对钢球摩擦表面膜的组成和化学状态的影响。结果表明:含氮硼酸酯添加剂具有良好的极压抗磨效果。在钢球磨损表面发现含有硼元素,表明在摩擦过程中,通过物理吸附和化学反应在摩擦表面生成了含硼的润滑膜,起到了极压抗磨的作用。

Abstract: A novel nitrogen-containing boric acid ester was synthesized from fatty acid methyl ester to be used as lubricant additive. The synthesized additive was characterized by FT-IR technique and its tribological performance in various base oils, e.g. the effect of friction time and load on PB value and wear scar diameter (WSD), were investigated using a four-ball tester. The morphologies of the worn scars were analyzed by means of scanning electron microscopy and energy dispersive X-ray spectroscopy to study the effect of said novel additive on the compositions and chemical states of the friction surface film.Results showed that this nitrogen-containing boric acid ester additive exhibited excellent extreme pressure anti-wear performance. Boron was detected from the worn surface of tested steel ball, which indicated that a lubricating film containing boron was formed on the friction surface by physical adsorption and chemical reaction, resulting in an enhancement of extreme pressure anti-wear function.