石油炼制与化工 ›› 2012, Vol. 43 ›› Issue (9): 25-28.

• 基础研究 • 上一篇    下一篇

延迟焦化低硅消泡剂的研制

赵蓓蓓1,杨超2,张喜文2   

  1. 1. 辽宁石油化工大学化学与材料科学学院   2. 中国石化抚顺石油化工研究院
  • 收稿日期:2011-12-05 修回日期:2011-12-27 出版日期:2012-09-12 发布日期:2012-08-29
  • 通讯作者: 张喜文 E-mail:zhangxiwen.fshy@sinopec.com

PREPARATION OF LOW-SILICON DEFOAMING AGENT FOR DELAYED COKING

  • Received:2011-12-05 Revised:2011-12-27 Online:2012-09-12 Published:2012-08-29

摘要: 研制了一种用于延迟焦化过程的低硅消泡剂,该消泡剂是以聚醚改性聚硅氧烷为主体复配而成。以含氢硅油与聚醚为原料,催化合成了聚醚改性聚硅氧烷;考察了反应时间、反应温度、物料配比、催化剂用量对反应的影响,确定了最佳合成条件,即含氢硅油中的Si—H与聚醚中的—OH的摩尔比为1:(1.4~1.6)、催化剂FA-2的质量分数为0.4 %、反应温度为110 ℃、反应时间为8 h。评价结果表明,所制备的聚醚改性聚硅氧烷及其复配物的消泡及抑泡性能良好。

Abstract: A low-silicon defoaming agent for delayed coking was developed, which is a complex additive package containing polyether modified polysiloxane mainly. The polyether modified polysiloxane was prepared from hydrogenous silicone oil and polyether, with FA-2 as catalyst. The influences of reaction conditions, such as reaction time, reaction temperature, the ratio of reagents and catalyst dosage were studied, and the optimum conditions were obtained as follows: the mole ratio of Si-H in hydrogenous silicone oil and –OH in polyether was in the range of (1:1.4)—(1:1.6), the mass fraction of catalyst was 0.4 %, reaction was proceeded at 110 ℃ for 8 h. Performance evaluation results showed that the prepared polyether modified polysiloxane and its complex exhibited good antifoaming and suppressing foam performance.