石油炼制与化工 ›› 2013, Vol. 44 ›› Issue (12): 91-94.

• 油品与添加剂 • 上一篇    

聚α-烯烃润滑油基础油热氧化安定性试验研究

程治升,费逸伟,胡建强,姚婷   

  1. 空军勤务学院航空油料重点工程实验室
  • 收稿日期:2013-05-06 修回日期:2013-06-17 出版日期:2013-12-12 发布日期:2013-11-20
  • 通讯作者: 程治升 E-mail:1157065920@qq.com

STUDY ON THERMAL OXIDATION STABILITY OF PAO BASE-OIL

  • Received:2013-05-06 Revised:2013-06-17 Online:2013-12-12 Published:2013-11-20

摘要: 采用润滑油薄层油膜微氧化试验与红外光谱分析联用技术,模拟合成航空润滑基础油聚α-烯烃在设定条件下的氧化后沉积物含量、油样质量损失与甲基吸收峰的红外光谱面积比(CSI)随氧化时间的变化关系。结果表明:油样经氧化90 min后即开始产生沉积物,随着氧化时间的延长,油样的质量损失和沉积物含量逐渐增加;氧化油样的CSI值先增大后减小,氧化程度逐渐加深,在230 ℃下良好的热氧化安定性可保持90 min左右。

Abstract: By combining thin micro oxidation test and infrared spectrum analysis, the relations of the sediment content,mass reduction under the setting oxidation conditions with oxidation time were simulated and analyzed. It can be seen that the deposit appears after 90 minutes oxidation and increases with the extension of time. It is discovered that the ratio of carbonyl and methyl group infrared spectrum areas of PAO (CSI) can well reflect the depth of oil oxidation. The ratio first increases and then decreases as the oxidation time is extended. The results show that the good thermal oxidation stability of PAO lubricating base-oil can keep about 90 minutes at 230 ℃.