石油炼制与化工 ›› 2013, Vol. 44 ›› Issue (4): 86-90.

• 分析与评定 • 上一篇    下一篇

塔河原油中有机氯来源分析和脱除

王振宇,王征,沈明欢,李本高   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2012-07-18 修回日期:2012-07-30 出版日期:2013-04-12 发布日期:2013-06-05
  • 通讯作者: 王振宇 E-mail:wangzy.ripp@sinopec.com

SOURCE AND REMOVAL OF ORGANIC CHLORIDE IN TAHE CRUDE OIL

  • Received:2012-07-18 Revised:2012-07-30 Online:2013-04-12 Published:2013-06-05

摘要: 通过对塔河稠油中氯盐的存在形态进行分析,发现其中不仅存在无机氯盐,而且存在有机氯盐,有机氯盐所占的比例在50%以上。用常规水洗脱盐的方法不能彻底脱除有机氯盐。有机氯盐在蒸馏过程中主要进入渣油中。开发了有针对性的脱氯助剂H,考察了脱氯助剂H对塔河原油的脱氯效果和对破乳过程的影响。结果表明,脱氯助剂H与破乳剂联合使用可以将脱后油的总氯质量分数降低到10 ?g/g以下,盐(NaCl)质量浓度降低到3 mg/L以下,并对破乳过程无不利影响。

Abstract: The existing forms of chloride salt in Tahe crude oil and their sources were analyzed and an assistant agent H for organic chloride removal was developed and tested. It is found that there are two forms of chloride salts in Tahe crude oil: inorganic and organic chloride and that the content of organic chloride is above 50%. The organic chloride cannot be completely removed by traditional method and mainly goes into residual oil fraction during distillation. The test results show that the agent H with demulsifier together can decrease the chloride content in treated oil to less than 10 ?g/g and salt content to less than 3 mg NaCl/L. Meanwhile it has little disadvantageous effect on demulsification.