石油炼制与化工 ›› 2013, Vol. 44 ›› Issue (9): 66-72.

• 加工工艺 • 上一篇    下一篇

催化裂化汽油加氢改质GARDES技术的开发及工业试验

石冈1,范煜1,鲍晓军2,王廷海3   

  1. 1. 中国石油大学(北京)中国石油天然气集团公司催化重点实验室
      2. 中国石油大学(北京)重质油国家重点实验室
      3. 中国石油石油化工研究院兰州化工研究中心
  • 收稿日期:2013-01-11 修回日期:2013-03-11 出版日期:2013-09-12 发布日期:2013-08-27
  • 通讯作者: 鲍晓军 E-mail:baoxj@cup.edu.cn
  • 基金资助:

    国家重点基础研究计划(973计划)项目;国家科技支撑项目

DEVELOPMENT AND APPLICATION OF GARDES TECNOLOGY FOR FLUID CATALYTIC CRACKING GASOLINE HYDRO-UPGRADING

  • Received:2013-01-11 Revised:2013-03-11 Online:2013-09-12 Published:2013-08-27

摘要: 介绍针对催化裂化(FCC)汽油清洁化开发的深度加氢脱硫和烯烃定向转化相耦合的FCC汽油加氢改质GARDES技术的工艺配置、催化剂的设计理念、工业试验情况及满足国IV排放标准兼顾满足国V排放标准的清洁汽油的中试评价情况。工业试验标定结果表明:所得产品可作为满足国IV排放标准的清洁汽油调合组分,在烯烃体积分数降低16百分点的情况下,辛烷值损失为1.0个单位。对于不同硫含量FCC汽油的中试评价结果表明:在目标产品为满足国IV排放标准要求的清洁汽油调合组分时,脱硫率为69%~89%、辛烷值损失为0.3~0.5个单位;在目标产品为满足国V排放标准要求的清洁汽油调合组分时,脱硫率为88%~96%、辛烷值损失为0.7~0.9个单位。

Abstract: With the aim of producing clean gasoline from fluid catalytic cracking (FCC) naphtha with higher sulfur and olefin contents,a GARDES technology for hydro-upgrading FCC naphtha was developed by coupling the deep desulfurization and directed olefin conversion. This article introduced the process configuration, catalyst design, and industrial results of the GARDES technology and then presented some pilot-plant results for producing clean gasoline fraction that meets the China IV and V standards. The industrial results show that the hydro-upgraded naphtha can be used as a blend component for the China IV gasoline pool with olefin reduction of 16 v% and ON loss<1 unit. The pilot plant evaluation demonstrate that at HDS of 69%~89%, the product can be used as a blend component for the China IV gasoline pool with ON loss of 0.3~0.5;while at HDS of 88%~96%,the product can be used as a blend component for the China V gasoline pool with ON loss of 0.7~0.9.