石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (3): 46-50.

• 加工工艺 • 上一篇    下一篇

Lurgi甲醇制丙烯技术的工业应用

王峰,张伟,雍晓静,罗春桃   

  1.  神华宁夏煤业集团有限责任公司煤炭化学工业分公司研发中心
  • 收稿日期:2013-08-14 修回日期:2013-11-19 出版日期:2014-03-12 发布日期:2014-02-21
  • 通讯作者: 王峰 E-mail:wang.feng@sngcc.com
  • 基金资助:

    国际科技与交流专项资助项目;宁夏回族自治区科技支撑计划项目(2013)

COMMERCIAL APPLICATION OF LURGI MTP TECHNOLOGY

  • Received:2013-08-14 Revised:2013-11-19 Online:2014-03-12 Published:2014-02-21

摘要: 介绍了Lurgi 甲醇制丙烯(MTP)工艺的技术特点及在神华宁夏煤业集团工业应用的情况。通过技术改造和优化,解决了激冷水泵汽蚀、工艺蒸汽中钠离子和丙烯中水含量超标等问题,提升了工艺蒸汽塔产能,实现了MTP装置满负荷运行,但仍然存在MTP反应器结构复杂、物料分布不均、工艺蒸汽塔蒸汽产能不足等问题。工业运行结果表明:丙烯收率比设计值偏低1.5~9.8百分点,而副产的液化气和燃料气收率偏高;副产的汽油馏分呈现正构烷烃含量低、芳烃含量高的特点,与常规FCC汽油组成差异较大;MTP催化剂使用寿命小于8 000 h,平均单程寿命仅为640 h ~700 h,需要反复再生。

Abstract: The characteristics and commercial application of Lurgi`s methanol-to-propylene (MTP) technology in Shenhua Ningxia Co, Ltd. was introduced. Through the technical improvement and optimization, some of the problems in this process, such as the cavitation of chilling water pump, the over standard Na+ amount in process steam and water in propylene were solved, resulting in improved capacity of the process steam tower and full load operation of the MTP device. But there are still some problems in the process: the complex structure of MTP reactors, the uneven distribution of materials, and the insufficient capacity of the process steam tower. The industrial operation results show that the propylene yield is about 1.5 %~9.8 % lower than the designed value, while the yields of liquefied petroleum gas and fuel gas are higher. Gasoline fraction obtained from Lurgi’s MTP reaction is characterized by low normal alkane and high aromatic content. The composition of the MTP gasoline is quite different from that of the conventional FCC gasoline. The total life of MTP catalyst is less than 8 000 h, and its regeneration cycles is only about 640-700 h.