石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (3): 67-70.

• 催化剂 • 上一篇    下一篇

PS-VI重整催化剂运行初期与末期性能分析

蒋项羽   

  1. 中国石化镇海炼化分公司
  • 收稿日期:2013-10-14 修回日期:2013-11-29 出版日期:2014-03-12 发布日期:2014-02-21
  • 通讯作者: 蒋项羽 E-mail:jiangxy.zhlh@sinopec.com

PERFORMANCE ANALYSIS OF PS-VI CONTINUOUS REFORMING CATALYST AT SOR AND EOR

  • Received:2013-10-14 Revised:2013-11-29 Online:2014-03-12 Published:2014-02-21

摘要: 阐述了PS-VI型连续重整催化剂在中国石化镇海炼化分公司0.8 Mt/a连续重整装置上工业应用的情况。为全面考察该催化剂的性能,分别在催化剂运行初期(15个运行周期)和末期(541个运行周期)对装置进行了性能标定。结果表明:随着使用时间延长,催化剂比表面积从运行初期的187 m2/g下降至末期的143 m2/g,铁质量分数从运行初期的280 ?g/g上升至末期的2 400 ?g/g,从而导致运行末期催化剂活性比初期下降4.1℃,稳定汽油收率下降1.77百分点,芳烃收率下降1.13百分点,氢气产率下降0.2百分点,装置的效益下降2 813.6万元/a。从换剂的技术经济性方面考虑,连续重整催化剂的使用不应该盲目追求时间长,应以实现炼油厂的经济效益最大化为目标,结合目前装置4年一修的运行周期,建议考虑4年更换一次催化剂。

关键词: 连续的 , 催化重整 , 催化剂, 性能, 运转周期

Abstract: This article expounds the commercial application of PS-VI catalyst (RC011), developed by Research Institute of Petroleum Processing, in the 0.8 Mt/a continuous reforming unit (CRU) of SINOPEC Zhenhai Refining and Chemical Company (ZRCC). In order to examine if the activity and selectivity has changed, the calibrations of the unit are conducted at its SOR and EOR stages. It is discovered that after running for 541 operation cycles, the surface area of the catalyst decreases from 187 m2/g at SOR to 143 m2/g at EOR and iron content increases form 280 ?g/g at SOR to 2 400 ?g/g at EOR, resulting in decrease of the catalyst activity by 4.1℃ and the selectivity of the stabilized gasoline, aromatics and H2 yield decreases 1.77%, 1.13% and 0.2%, respectively. These changes result in the benefit of the device falling 28.136 million yuan/a. It is suggested that the replacement of the catalyst be once every 4 years to keep pace with the factory overhaul cycle every four-years.

Key words: continuous, catalytic reforming, catalyst, performance, operation cycles