石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (4): 56-59.

• 加工工艺 • 上一篇    下一篇

催化热裂解石脑油两段加氢生产芳烃抽提原料技术的工业应用

吴小平,王兴军,王东松   

  1. 沈阳石蜡化工有限公司
  • 收稿日期:2013-10-11 修回日期:2013-11-28 出版日期:2014-04-12 发布日期:2014-03-24
  • 通讯作者: 吴小平 E-mail:wxp20052516@163.com

COMMERCIAL APPLICATION OF TWO-STAGE HYDROGENATION FOR PRODUCING AROMATIC EXTRACTION MATERIALS FROM PYROLYSIS NAPHTHA

  • Received:2013-10-11 Revised:2013-11-28 Online:2014-04-12 Published:2014-03-24

摘要: 沈阳石蜡化工有限公司针对催化热裂解(CPP)制乙烯装置生产的裂解石脑油含有大量的单烯烃、双烯烃、烯基芳烃、茚等不饱和烃以及硫、氮、氧等有机化合物,导致其性质很不稳定,易于缩合形成胶质的情况,在国内首次选用两段加氢工艺,对CPP石脑油进行加氢处理,生产出满足芳烃抽提装置要求的原料,并产出合格芳烃产品。工业运行结果表明,该技术可靠,各单元操作平稳,运行良好。

关键词: 催化热裂解, 石脑油 , 加氢处理 , 芳烃抽提, 工业试验

Abstract: catalytic pyrolysis cracking (CPP) naphtha contains a large quantity of mono-olefin, di-olefin, alkenyl aromatic, indene and other unsaturated hydrocarbons as well as sulfur, nitrogen, oxygen in organic compound. It can result in unstable cracking naphtha, which tends to form condensate like resin and impurities. However, CPP naphtha can be treated by two stage hydrogenation process to produce on-specified aromatic extraction raw material. The first time commercial test shows that the two stage hydrogenation technology for producing aromatic extraction materials from pyrolysis naphtha is reliable and stable.

Key words: catalytic pyrolysis, naphtha, hydrogenation, aromatic extraction, commercial trial