石油炼制与化工 ›› 2014, Vol. 45 ›› Issue (8): 54-57.

• 加工工艺 • 上一篇    下一篇

加氢异构脱蜡反应温度的影响因素研究

黄小珠,李鸣,宫卫国,王泽爱   

  1. 中海油能源发展股份有限公司惠州石化分公司
  • 收稿日期:2014-01-08 修回日期:2014-02-21 出版日期:2014-08-12 发布日期:2014-07-22
  • 通讯作者: 黄小珠 E-mail:huangxzh1@126.com
  • 基金资助:

    中海油能源发展股份有限公司科技项目

STUDY OF FACTORS AFFECTING HYDROGENATION ISOMERIZATION DEWAXING REACTION TEMPERATURE

  • Received:2014-01-08 Revised:2014-02-21 Online:2014-08-12 Published:2014-07-22

摘要: 中海油能源发展股份有限公司惠州石化分公司引进Chevron公司开发的加氢异构脱蜡专利技术,投资建设了400 kt/a加氢异构脱蜡装置,以加氢裂化尾油为原料,在反应压力和氢油比相近的条件下,研究了加氢裂化尾油进料量、原料中蜡质量分数和主产品150N基础油的倾点对反应温度的影响。结果表明,对于同一种原料,为达到150N基础油性质相同,进料量每提高1t/h,反应温度需提高约0.5 ℃;而在进料量稳定的情况下,150N基础油的倾点每降低1 ℃,反应温度需提高1.2 ℃左右;当进料量和150N基础油性质相同时,采用蜡含量越大的原料,则所需反应温度越高。

Abstract: Huizhou petrochemical company of CNOOC energy development Ltd introduced the hydroisomerization dewaxing technology developed by Chevron Company and invested in the construction of a 400 kt/a hydroisomerization dewaxing unit. The hydrocracking tail oil is used as a raw material. Under the same reaction pressure and hydrogen/oil ratio conditions, the effect of the feed rate and its wax content, and pour point of main product (150N base oil) on the reaction temperature were tested. The results show that in order to achieve the same properties of 150N base oil using the same kind of raw material, the reaction temperature is increased by about 0.5 ℃ for every increase of feed rate 1t/h; and that in the case of stable feeding quantity, reaction temperature needs to increase by about 1.2 ℃ for every 1℃ reduction of pour point of 150 base oil. When the feed rate and the property of base oil 150N remain unchanged, the reaction temperature increases with increasing wax mass faction of the feed.