石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (1): 62-67.

• 加工工艺 • 上一篇    下一篇

GARDES技术在汽油加氢脱硫装置的工业应用

许长辉   

  1. 中国石油大庆石化公司炼油厂
  • 收稿日期:2014-06-11 修回日期:2014-07-07 出版日期:2015-01-12 发布日期:2014-12-18
  • 通讯作者: 许长辉 E-mail:lyxch@petrochina.com.cn

APPLICATION OF GARDES TECHNOLOGY IN FCC NAPHTHA HYDRODESULFURIZATION UNIT

  • Received:2014-06-11 Revised:2014-07-07 Online:2015-01-12 Published:2014-12-18

摘要: 介绍了中国石油石油化工研究院和中国石油大学(北京)联合开发的GARDES技术在中国石油大庆石化公司炼油厂汽油加氢脱硫装置上的工业应用情况。结果表明:催化裂化汽油预加氢处理后二烯值降低到0.45 gI/(100 g)以下,分馏后轻汽油硫醇硫质量分数小于3 μg/g,可直接用于汽油调合,无需碱液脱硫醇处理,催化裂化汽油硫质量分数由97~103 μg/g降至26 μg/g,脱硫率为74%;产品汽油硫醇硫质量分数小于10 μg/g,平均RON损失仅为0.3个单位,可以用于生产满足国Ⅳ标准的清洁汽油组分。

关键词: 催化裂化汽油 , 加氢脱硫 , GARDES技术, 辛烷值

Abstract: The application of GARDES technology developed by PetroChina Petrochemical Institute and China University of Petroleum (Beijing) in FCC gasoline hydrodesulfurization unit of Daqing Petrochemical Company Refinery was introduced. The results show that the diene value of FCC gasoline is less than 0.45 gI/(100g) after prehydrotreating. The mercaptane sulfur content of LCN is less than 3μg/g, which can be blended into gasoline directly without alkali sweetening process. The sulfur content of FCC gasoline after HDS is decreased from 97~ 103μg/g to 26μg/g, the sulfur removal rate is 74 %. The mercaptane sulfur content in final product is less than 10μg/g, and the average octane loss is only 0.3 point. The GARDES technology can produce clean national phase IV standard gasoline.

Key words: FCC naphtha, hydrodesulfurization, GARDES technology, octane number