石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (12): 73-76.

• 油品与添加剂 • 上一篇    下一篇

变压器油碳型组成对氧化安定性的影响

张绮,马书杰,于会民,王会娟   

  1. 中国石油兰州润滑油研究开发中心润滑油重点实验室(克拉玛依)
  • 收稿日期:2015-05-08 修回日期:2015-06-15 出版日期:2015-12-12 发布日期:2015-11-26
  • 通讯作者: 张绮 E-mail:zhangqi_rhy@petrochina.com.cn

INFLUENCE OF DIFFERENCE TYPE CARBON COMPOSITION ON OXIDATION STABILITY OF NAPHTHENIC BASE TRANSFORMER OILS

  • Received:2015-05-08 Revised:2015-06-15 Online:2015-12-12 Published:2015-11-26

摘要:

采用快速评定方法高压差式量热扫描(PDSC)以及NB/SH/T 0811方法对碳型组成不同的环烷基变压器油进行了氧化安定性评定,以考察变压器油芳烃含量对氧化安定性能的影响。结果表明,对于加抗氧剂变压器油,其精制深度越高、芳烃含量越低,对抗氧剂感受性越好,氧化安定性就越好。但为了平衡变压器油溶解性能和抗氧化性能,以及在抗氧剂消耗后仍具有较好的抗氧化性能,变压器油应保持一定的精制深度和一定的芳烃含量。

关键词: 变压器油, 氧化安定性, 碳型组成

Abstract:

The effect of aromatic content on the oxidation stability of naphthenic base transformer oils with different carbon type compositions were detected using high pressure differential calorimeter scans (PDSC) and NB/SH/0811 method. The experimental results show that for transformer oils with anti-oxidant, the deeper the refining depth and the lower the aromatic content, the better the anti-oxidant sensitivity, also the better the oxidation stability. But in order to balance the dissolved performance and oxidation resistance after hydrotreatment, and to have a better anti-oxidation after the consumption of anti-oxidant, it is necessary to keep a certain refining depth and contain a certain amount of aromatic hydrocarbons for hydrotreated oils.

Key words: transformer oil, oxidation stability, carbon type composition