石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (3): 34-38.

• 催化剂 • 上一篇    下一篇

LS-951T硫磺回收尾气加氢催化剂的工业应用

路蒙蒙,宋寿康,杨同民,崔笑   

  1. 中化泉州石化有限公司
  • 收稿日期:2014-08-26 修回日期:2014-10-21 出版日期:2015-03-12 发布日期:2015-02-13
  • 通讯作者: 路蒙蒙 E-mail:lumengmeng84@126.com

APPLICATION OF LS-951T HYDROGENATION CATALYST FOR SULFUR RECOVERY TAIL GAS TREATMENT

  • Received:2014-08-26 Revised:2014-10-21 Online:2015-03-12 Published:2015-02-13

摘要: LS-951T催化剂是中国石化齐鲁分公司研究院新开发的硫磺回收尾气加氢催化剂,该催化剂具有活性组分分布均匀、堆密度轻和加氢活性高等优点,具有较强的工艺适用性。通过该催化剂在中化泉州石化有限公司380 kt/a硫磺回收尾气处理装置上的工业应用,介绍了催化剂的特点、装填和超前硫化情况,对比分析了该催化剂在硫磺回收装置高、低负荷下的运行情况;针对高负荷下加氢催化剂易流动的问题,对加氢反应器催化剂的装填进行了整改。整改后的应用结果表明,在高负荷下,该催化剂具有较高的加氢活性,排放尾气中的SO2含量小于300 mg/m3,远远低于960 mg/m3,满足国家要求的排放标准。

关键词: 硫磺回收, 尾气, 加氢, 催化剂

Abstract: LS-951T catalyst developed by Research Institute of Qilu Petrochemical Company is a new hydrogenation catalyst for treating sulfur recovery tail gas. LS-951T catalyst, with the advantages of uniform distribution of active components, light bulk density and high hydrogenation activity, has a good applicability. The properties of the catalyst and the commercial processes of catalyst loading, presulfurization in a 380kt/a sulfur recovery tail gas unit in Sinochem Quanzhou Petrochemical Co.,Ltd were described. The performance of the catalyst was examined and compared in low and high load operation case.The loading pattern of LS-951T catalyst was modified because it’s easy to flow in the later case. The application results after modification of loading show that the catalyst presents good hydrogenation activity ever if in high load case. The SO2 content is less than 300mg/m3 in the treated gas, lower than the country’s emission standard of 960mg/m3.

Key words: sulfur recovery, tail gas, hydrogenation, catalyst