石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (3): 92-96.

• 分析与评定 • 上一篇    

原油盐含量测定的影响因素分析

李瑞丽,张平,吕本震,李晶晶   

  1. 中国石油大学(北京)重质油国家重点实验室
  • 收稿日期:2014-08-18 修回日期:2014-10-21 出版日期:2015-03-12 发布日期:2015-02-13
  • 通讯作者: 张平 E-mail:zhangpingzpfc@163.com

FACTORS AFFECTING DETERMINATION OF SALT CONTENT OF CRUDE OIL

  • Received:2014-08-18 Revised:2014-10-21 Online:2015-03-12 Published:2015-02-13

摘要: 针对目前国内普遍采用的SY/T 0536电量法,采用WC-200型微机盐含量测定仪对影响原油盐含量测定的主要因素进行考察,结果表明,WC-200型微机盐含量测定仪的最佳工作条件为偏压260 mV、转化率84%、积分电阻2 K、增益2400,在此条件下测定盐质量浓度分别为3,5,10,20,50,100 mg/L的6种不同浓度的标样,相对误差均小于2%,满足仪器使用要求(相对误差小于5%);对来自不同炼油厂的13种原油样品,盐含量测定结果的标准偏差SD≤1.150 mg/L,相对标准偏差RSD≤2.63%,均满足仪器使用要求。

Abstract: At present SY/T 0536 method is widely used to measure the salt content of crude oils at home. This work introduces the application of WC-200 microcomputer in this aspect and some factors influencing measuring results were discussed. The results show that bias voltage, conversion rate, integral resistor, and magnification gain has a great influence on the accuracy of the measurement. The optimal conditions using WC-200 microcomputer are bias voltage of 260 mv, conversion rate of 84%, integral resistor of 2 K and gain of 2 400. At optimal conditions, samples with salt content of 3,5,10,20,50,100 mg/L were measured to see the accuracy of the WC-200 microcomputer method. The results show that the relative errors are less than 2%, satisfied with the standard deviation of 5% of instrument in concentration range. The salt contents of thirteen kinds of crude oils from different sources were analyzed. The standard deviations are SD≤1.150 mg/L, less than the relative standard deviation of RSD≤2.63% of the instrument requirement.