Abstract: With organic silicon and titanium, a new shell-type titanosilicate sieve (RTS) was synthesized by two step hydrothermal crystallization method. The physical properties and catalytic oxidation performance of RTS was characterized by various analytic instruments and phenol hydroxylation reaction. The results show that RTS has MFI topological structure, and the Ti species in RTS are mainly on the shell part of particles. The catalytic performance results indicate that RTS gives the same catalytic oxidation activity and benzene diol selectivity as that of TS-1, and the reusable performance is better than that of TS - 1.