石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (8): 1-6.

• 加工工艺 •    下一篇

重油催化裂解多产轻质芳烃工艺的研究

马文明,李小斐,朱根权,谢朝钢   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2015-02-02 修回日期:2015-03-11 出版日期:2015-08-12 发布日期:2015-07-27
  • 通讯作者: 谢朝钢 E-mail:xiecg@ripp-sinopec.com
  • 基金资助:

    中国石油化工股份有限公司合同项目

STUDY ON INCREASING LIGHT AROMATICS PRODUCTION IN DEEP CATALYTIC CRACKING OF HEAVY OIL

  • Received:2015-02-02 Revised:2015-03-11 Online:2015-08-12 Published:2015-07-27

摘要: 以管输蜡油为原料,考察了重油催化裂解条件下反应温度、剂油质量比、质量空速和水油质量比等不同操作条件对产物分布、低碳烯烃和轻质芳烃收率的影响,得到适宜的反应条件为:反应温度560 ℃,剂油质量比6,质量空速2 h-1,水油质量比10。对比了大庆蜡油和管输蜡油在相同操作条件下发生裂化反应时低碳烯烃和轻质芳烃的收率,得出随着反应深度的加大,石蜡基原料的轻质芳烃收率增长速率更快,大剂油比条件下生产的轻质芳烃甚至更多, 可以兼顾多产低碳烯烃和轻质芳烃。讨论了催化裂化反应中轻质芳烃的生成与转化途径,当转化深度较小时,轻质芳烃的来源以芳烃迁移反应为主,随着转化深度的增大,烯烃环化脱氢生成轻质芳烃的速率逐渐超过芳烃迁移反应。

Abstract: The effect of reaction temperature, catalyst/oil ratio, WHSV, and water/oil mass ratio on product distribution, light olefins and light aromatics yields was investigated using pipeline VGO as a feedstock. The best process parameters are: 560 ℃, ratio of catalyst to oil (C/O) of 6, WHSV of 2h-1 and water to oil (W/O) of 10. Daqing VGO and intermediated pipeline VGO were employed as cracking feedstocks to examine how feedstock properties impact on the yields of light olefins and light aromatics under the same conditions. The results indicate that the paraffin based feedstock is better in maximizing yields of light olefins and light aromatics, even more light aromatics can be produced at larger catalyst/oil ratio. Using paraffin base VGO, more light olefins and aromatics can be obtained simultaneously. The pathway of light aromatics formation was investigated. It is discovered that most light aromatics are formed by breaking side chain of the mononuclear aromatics when the conversion is low, while the light aromatics from dehydrocyclization of olefins becomes gradually the main pathway when the conversion is higher.