石油炼制与化工 ›› 2015, Vol. 46 ›› Issue (9): 12-15.

• 催化剂 • 上一篇    下一篇

绥中361蜡油生产SBS填充油的催化剂配套体系研究

任建松,马莉莉,徐萌   

  1. 中海油气开发利用公司
  • 收稿日期:2015-02-09 修回日期:2015-03-18 出版日期:2015-09-12 发布日期:2015-08-19
  • 通讯作者: 任建松 E-mail:renjs2@cnooc.com.cn

STUDY ON CATALYST SYSTEM FOR SBS RUBBER EXTENDER OIL PRODUCTION FROM SUIZHONG 361 VGO

  • Received:2015-02-09 Revised:2015-03-18 Online:2015-09-12 Published:2015-08-19

摘要: 针对中海油绥中361减二线蜡油、减三线蜡油原料,考察非贵金属降凝-非贵金属补充精制、非贵金属降凝-贵金属补充精制、贵金属异构脱蜡-贵金属补充精制三种催化剂体系下生产SBS填充油的产品质量和收率。实验结果表明:产品的倾点相当;后两者的光安定性和热安定性相当,且远好于非贵金属体系;三者收率相差不大,以贵金属脱蜡-贵金属补充精制催化剂体系最高,对于减二线和减三线原料,贵金属异构脱蜡-贵金属补充精制催化剂体系所制得的产品收率比其它两个催化剂体系制得的产品收率分别高出1.4百分点和2.3百分点。工业装置应根据市场价格,通过经济核算在非贵金属降凝-贵金属补充精制和贵金属脱蜡-贵金属补充精制两种体系之间作出选择。

关键词: 环烷基, 润滑油, 异构脱蜡, 临氢降凝, SBS填充油

Abstract: Three catalyst systems: non-noble metal dewaxing-non-noble metal hydrofinishing, non-noble metal dewaxing-noble metal hydrofinishing, and noble metal dewaxing-noble metal hydrofinishing, were tested for production of SBS rubber extender oil from CNOOC Suizhong-361 VGO#2 & VGO#3. No much difference in product yield for the three catalyst systems was observed at similar product pour point; however, the noble metal dewaxing-noble hydrofinishing catalyst system indeed offers a higher yield, 1.4 percentage points and 2.3 percentage points higher than that of other two catalyst systems, respectively. Products from the two catalyst systems with noble metal have much better light and thermal stability than that of the non-noble metal catalysts. It is concluded that for industry unit, the selection of catalyst system depends on the consideration of the market needs and economic evaluation.

Key words: naphthenic base, lubricant, hydroisodewaxing, hydrodewaxing, SBS rubber extender oil