酯类基础油热氧化机理研究

石油炼制与化工 ›› 2016, Vol. 47 ›› Issue (11): 89-94.

酯类基础油热氧化机理研究

葛龙龙,梁宇翔,贺景坚

中国石化石油化工科学研究院

收稿日期:2016-04-13 修回日期:2016-06-14 出版日期:2016-11-12 发布日期:2016-10-27
通讯作者: 葛龙龙 E-mail:411640738@qq.com
基金资助:

STUDY ON THERMAL OXIDATION MECHANISM OF ESTER BASE OIL

Received:2016-04-13 Revised:2016-06-14 Online:2016-11-12 Published:2016-10-27
Supported by:

摘要/Abstract

摘要： 选用新戊二醇二庚酸酯作为模型化合物，模拟酯类航空基础油高温条件下的热氧化、分解、聚合等过程。通过分子模拟计算模型化合物分子的各个键能，检测其氧化、裂解、聚合产物的组分，油品酸值、黏度等物化性能的变化，分析其氧化机理，对研究酯类润滑油的热氧化机理提供基础数据。

关键词: 航空润滑油, 液相结焦, 酯类基础油, 高温氧化, 分子模拟

Abstract: The neopentyl glycol diheptanoate was used as a model compound to simulate the thermal oxidation, decomposition and polymerization process of ester aviation base oil at high temperature. Molecular simulation was used to calculate the molecular bond energy of the model compound. Based on the results of oxidation, pyrolysis, polymerization, and the changes of acid value and viscosity, the oxidation mechanism of the model compound was proposed to provide the basic data for the study of the thermal oxidation mechanism of ester lubricating oil.

Key words: aviation lubricating oil, liquid coking, ester base oil, high temperature oxidation, molecular simulation

中图分类号:

葛龙龙梁宇翔贺景坚. 酯类基础油热氧化机理研究[J]. 石油炼制与化工, 2016, 47(11): 89-94.

参考文献

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