无硫磷有机钼对不同基体材料的润滑效果研究

石油炼制与化工 ›› 2016, Vol. 47 ›› Issue (12): 80-86.

无硫磷有机钼对不同基体材料的润滑效果研究

井致远,许一,张伟,尹艳丽

装甲兵工程学院装备与制造技术国防科技重点实验室

收稿日期:2016-05-04 修回日期:2016-06-27 出版日期:2016-12-12 发布日期:2016-11-29
通讯作者: 许一 E-mail:zjbgcxuyi@163.com
作者简介:2016-09-03
基金资助:

LUBRICATING EFFECT OF SULFUR-AND PHOSPHORUS-FREE ORGANIC MOLYBDENUM ON DIFFERENT MATRIX MATERIALS

Received:2016-05-04 Revised:2016-06-27 Online:2016-12-12 Published:2016-11-29
Contact: Yi NoneXu E-mail:zjbgcxuyi@163.com
Supported by:

摘要/Abstract

摘要： 将不同添加量的无硫磷有机钼添加剂加入柴油机油中，利用SRV摩擦磨损试验机考察其在不同添加量下对45号钢和GCr15钢的减摩抗磨性能；采用电子扫描电镜（SEM）、X射线能谱仪（EDS）、光电子能谱（XPS）分析磨痕的表面形貌、元素组成及价态。结果表明：无硫磷有机钼在45号钢上的减摩性能随添加量的增大而提高，但抗磨性能降低，当添加量超过0.6%时，磨损体积甚至超过不添加无硫磷有机钼时的磨损体积；无硫磷有机钼在GCr15钢上的润滑效果远好于在45号钢上的润滑效果，且试验的摩擦因数和磨损体积均随添加剂添加量的增加而减小。添加无硫磷有机钼后,在摩擦过程中基体表面能够附着含铁和钼氧化物的边界润滑膜,起到润滑作用，但过量的无硫磷有机钼在45号钢表面形成MoO3磨粒,增大磨损体积，并导致基体表面氧化严重，发生严重磨损，加剧了磨损体积增大的趋势；而GCr15钢的硬度大，因此不会出现磨损体积增大的情况，无硫磷有机钼能够有效地起到抗磨作用。

关键词: 无硫磷有机钼, 基体材料, 减摩, 抗磨

Abstract: Different amounts of sulfur- and phosphorus-free organic molybdenum (SPFOM) additive were added into diesel engine oil to measure the friction reduction and anti-wear properties of SPFOM on No.45 steel and GCr15 steel using SRV friction wear machine. Scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) were employed to analyze the worn surface morphologies, elements with various valences. The test results show that the friction reduction property of SPFOM on No. 45 steel is improved with increasing additive amount, but the anti-wear property declines, and the wear volume is even larger than that of diesel engine oil without SPFOM when the additive amount is above 0.6%; the lubricating effect of SPFOM is much better on GCr15 steel than that on No. 45 steel, and both friction coefficient and wear volume decrease with the increasing of additive amount. Boundary lubricating film containing molybdenum and ferrous oxide is formed on the matrix surface during friction process with SPFOM in the oils, but too much SPFOM forms MoO3 particles, which increase wear volume of No. 45 steel, serious oxidation of the matrix surface, and wear trend. While the hardness of GCr15 steel is high enough to avoid the increase of wear volume, resulting in effective anti-wear for lubricating oil with SPFOM.

Key words: sulfur- and phosphorus-free organic Mo, matrix material, friction-reduction, anti-wear

中图分类号:

井致远许一张伟尹艳丽. 无硫磷有机钼对不同基体材料的润滑效果研究[J]. 石油炼制与化工, 2016, 47(12): 80-86.

参考文献

[1]谢欣，武志强，王立华，等.节能车用润滑油和发动机台架评定技术的进展[J].石油炼制与化工, 2011, 42(8):7-11 [2]胡建强，胡利明，胡役芹，等.非硫、磷有机钼添加剂在发动机油中的应用[J].合成润滑材料, 2006, 33(2):20-24 [3]郭志光，刘维民.新型无硫、磷有机钼化合物润滑油添加剂对钢钢摩擦副摩擦磨损性能影响研究[J].摩擦学学报, 2006, 26(2):97-101 [4]谢凤，胡建强，郑发正，等.非活性有机钼与二烷基二硫代磷酸锌的抗磨协同效应[J].石油学报石油加工, 2007, 23(2):24-29 [5]谢凤，王洋，郑发正，等.非活性有机钼与硫磷型添加剂的抗磨协同效应[J].润滑与密封, 2006, (4):129-132 [6]胡建强，刘长城，魏贤勇，等.有机钼酸脂与芳胺抗氧剂在合成润滑油中的抗氧协同作用[J].精细石油化工, 2007, 24(1):61-64 [7]胡建强，杨士钊，谢凤，等.非硫磷有机钼化合物与其它润滑油添加剂的协同性能研究[J].石油炼制与化工, 2013, 44(11):86-90 [8]曹聪蕊，刘功德，张润香，等.无硫磷型有机减摩剂的研究与应用进展[J].润滑油, 2011, 26(4):1-6 [9]叶红，武志强，闾邱祁鸣.利用高频往复试验机对内燃机油减摩剂减摩抗磨性能考察[J].润滑油, 2007, 22(6):25-30 [10]Arabyan SG, Holomonov IA, Karaulov AK, et al.An Investigation of the Effectiveness of Antifriction Additives in Motor Oils by Laboratory Methods and Engine Tests[J].Lubricant Science, 1993, 5(3):241-244 [11]高晓成，岳文，王成彪，等.含二烷基二硫代磷酸锌润滑下等离子渗氮钢的摩擦磨损性能研究[J].摩擦学学报, 2011, 31(6):592-598 [12]齐尚奎，薛群基，张旭寿，等.二硫化钼表面氧化行为的研究——二硫化钼摩擦表面氧化与电子转移的研究[J].摩擦学学报, 1994, 14(1):17-24 [13]Barros’Bouchet MI, Martin JM, Le-Mogne T, et al.Boundary Lubrication Mechanisms of Carbon Coating by MoDTC and ZDDP Additives[J].Tribology International, 2005, 38:257-264 [14]Miklozic KT, Graham J, Spikes H.Chemical and physical analysis of reaction ?lms formed by molybdenum dialkyl-dithiocarbamate friction modi?er additive using Raman and atomic force microscopy[J].Tribology Letters, 2001, 11(2):71-81 [15]郭永明，李绪强，王海军，等.超音速等离子喷涂-复合涂层的高温摩擦磨损性能[J].中国表面工程, 2012, 25(5):31-36 [16]Yao J B, Gaston A, Glenn A M.The Friction-Reducing,Antiwear and Antioxidation Properties of an Organo-Molybdenum Lube Additive without Sulfur and Phosphorus[J].Lubricating Oil, 2007, 22(3):43-48 [17]闫丽丽.新型无硫磷有机钼添加剂的制备与摩擦学性能研究[D]. 北京：中国地质大学, 2010. [18]Yan L L, Yue W, Wang C B, et al.Comparing tribological behaviors of sulfur- and phosphorus-free organomolybdenum additive with ZDDP and MoDTC[J].Tribology International, 2012, 53:150-158 [19]Haque T, Morina A, Neville A.In?uence of friction modi?er and antiwear additives on the tribological performance of a non-hydrogenated DLC coating[J].Surface & Coatings Technology, 2010, 204:4001-4011 [20]谢凤，刘书君，葛世荣，等.纳米三氧化钼的制备及其抗磨性能研究[J].润滑与密封, 2011, 36(8):71-73 [21]陈康敏，王树奇，杨子润，等.钢的高温氧化磨损及氧化物膜的研究[J].摩擦学学报, 2008, 28(5):475-479 [22]邓广勇，陆明，崔光淑.对润滑油中使用的抗氧剂及金属钝化剂的一点认识[J].润滑油, 2008, 23(5):48-51 [23]王树奇，崔向红.钢氧化磨损的轻微-严重磨损转变[J].材料研究学报, 2012, 26(1):1-7