›› 2016, Vol. 47 ›› Issue (4): 71-75.

• 油品与添加剂 • 上一篇    下一篇

柴油机油添加剂的稳定性研究

张倩1,安谧2   

  1. 1. 中国石化石油化工科学研究院
    2. 中国石油天然气股份有限公司石油化工研究院
  • 收稿日期:2015-10-27 修回日期:2015-12-01 出版日期:2016-04-12 发布日期:2016-04-19
  • 通讯作者: 张倩 E-mail:zhangqian.ripp@sinopec.com

STABILITY OF ADDITIVES IN DIESEL ENGINE OILS

  • Received:2015-10-27 Revised:2015-12-01 Online:2016-04-12 Published:2016-04-19

摘要: 采用沉淀值、溶解试验及微粒粒径测量等试验对柴油机油常用添加剂单剂和添加剂复配后体系的稳定性进行考察,并应用红外光谱分析、粒径分析及碰撞理论等手段对添加剂之间相互作用的机理进行了研究。结果表明:添加剂单剂中高碱值烷基苯磺酸钙的稳定性最差,其次为高碱值硫化烷基酚钙,其它添加剂的稳定性较好;高碱值烷基苯磺酸钙与高碱值硫化烷基酚钙复配时会产生大量沉淀,两者之间无化学反应发生,但颗粒相互碰撞,形成更大的颗粒,从而使体系不稳定;无灰分散剂的引入有利于高碱值烷基苯磺酸钙胶体结构的稳定,两者复配时,无灰分散剂利用其空间位阻效应使高碱值烷基苯磺酸钙的稳定性提高。

关键词: 添加剂, 稳定性, 胶体结构, 相互作用

Abstract: The stability of diesel engine oil additives is investigated with several methods associated with sediment and particle. Study shows that overbased calcium alkylbenzene sulfonate is found to have the most sediment and the largest particle diameter. A lot of sediment is found when overbased calcium alkylbenzene sulfonate mixes with overbased sulfurized calcium alkylphenolate because forming larger particles through collision of the small particles,resulting in unstable colloid system, but no interaction is occurred. The addition of ashless dispersants makes the overbased calcium alkylbenzene sulfonate more stable becaused of the space steric effect of the dispersant.

Key words: additive, stability, colloidal structure, interaction