›› 2016, Vol. 47 ›› Issue (6): 37-41.

• 基础研究 • 上一篇    下一篇

多环芳烃在催化裂化过程中的转化规律研究

刘银亮   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2016-04-12 修回日期:2015-12-04 出版日期:2016-06-12 发布日期:2016-06-02
  • 通讯作者: 刘银亮 E-mail:liuyinliang.ripp@sinopec.com

RESEARCH ON POLYCYCLIC AROMATIC HYDROCARBONS IN THE CATALYTIC CRACKING CONVERSION

  • Received:2016-04-12 Revised:2015-12-04 Online:2016-06-12 Published:2016-06-02

摘要: 在中型催化裂化装置上,采用MLC-500催化剂,以劣质直馏蜡油为原料,通过考察不同转化率条件下重芳烃在催化裂化重质馏分油(简称重油)中的传递系数,得到各类芳烃在催化裂化反应中的转化规律。结果表明:当多环芳烃转化率低于48.22%时,主要发生多环芳烃侧链断裂反应;转化率为48.22%~62.71%时,三环、四环芳烃在催化重油中的传递系数变化不大,芳核较为稳定,总多环芳烃在重油中的传递系数为0.3~0.4,此转化率区间为高选择性催化裂化合理区间;转化率高于62.71%时,多环芳烃缩合反应加剧,对生焦贡献率增加。

关键词: 多环芳烃, 焦炭 , 芳烃, 传递系数

Abstract: This research based on catalytic cracking pilot plants unit, the use of inferior straight-run gas oil as raw material, through change different conversion rate ,we can get the transfer coefficient of polycyclic aromatic hydrocarbons, test result may illustrate conversion rule of polycyclic aromatic hydrocarbons: under the condition of conversion rate below 48.22%, the transformation of polycyclic aromatic hydrocarbons, the main reaction as the branched chain rupture; when Conversion rate ranged from 48.22% to 62.71%, the three ring and the four ring aromatic hydrocarbons transfer coefficient changed little in the catalytic heavy oil, aromatic nucleus is relatively stable, polycyclic aromatic hydrocarbons transfer coefficient is about 0.3~0.4. the conversion rate is suitable for high selective catalytic cracking. When the conversion rate is higher than 62.71%, the polycyclic aromatic hydrocarbons will condensate rapidly, enhance the contributions to coke increases.

Key words: polycyclic aromatics, coke, aromatics, transfer coefficient