石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (1): 6-10.

• 加工工艺 • 上一篇    下一篇

塔河油破乳困难原因分析与对策

王振宇1,张金河2,姜辉2,吴振华2,沈明欢1,于丽1,李本高1   

  1. 1. 中国石化石油化工科学研究院25室
    2. 中国石化塔河分公司
  • 收稿日期:2016-05-17 修回日期:2016-08-09 出版日期:2017-01-12 发布日期:2016-12-26
  • 通讯作者: 王振宇 E-mail:wangzy.ripp@sinopec.com
  • 基金资助:
     

PROBLEM ANALYSIS OF TAHE CRUDE OIL DEMULSIFICATION AND COUNTERMEASURES

    

  1.  
  • Received:2016-05-17 Revised:2016-08-09 Online:2017-01-12 Published:2016-12-26
  • Contact: zhen-yu WANG E-mail:wangzy.ripp@sinopec.com
  • Supported by:
     

摘要: 针对塔河原油电脱盐过程中破乳效果不理想的情况,对2008—2014年塔河原油的性质进行了分析。结果表明,塔河原油性质呈现逐年劣质化的变化趋势,特别是沥青质含量上升、胶质与沥青质的质量比降低、机械杂质含量增加,这些变化是导致其破乳难度加大的主要原因。通过实验研究,将烷基酚醛聚醚A助剂与聚丙烯酸聚醚主剂复配,得到油溶性破乳剂RP-04;将05-M主剂与对含铁颗粒具有润湿作用的R30助剂复配,得到水溶性破乳剂RP-05。在加工塔河原油的某炼油厂3.5 Mt/a电脱盐装置上的工业应用试验结果表明,RP-04和RP-05联合使用时具有较好的破乳效果,在试验稳定期,可以将脱后原油的盐含量从试验前的10.5 mgNaCl/L降低到5~6 mgNaCl/L,能够实现在高注水和高混合强度条件下的正常破乳,而没有导致电流的突然升高。

关键词: 塔河稠油, 破乳, 脱盐, 机械杂质, 工业试验

Abstract: The properties of Tahe crude oil produced in 2008-2014 were analyzed to investigate the reasons for difficult demulsification. The analysis reveals a inferior trend in crude quality year by year due to increased asphaltene content and the mechanical impurities while decreased mass ratio of resin/asphaltene, which may be the reasons accounting for difficult demulsification of Tahe crude oil. The oil soluble demulsifier RP-04 was developed by mixing polyacrylate polyether, a main agent with alkyl phenolic polyether A, an aid agent. The water soluble demulsifier RP-05 was obtained by compositing the main agent 05-M with aid agent R30 which has the effect that makes the iron particles wetting. The RP-04 and RP-05 were used jointly in a 3.5 Mt/a desalting unit of a refinery. The results show that in the steady operation conditions of high water injection rate and high mixing intensity, the salt content of treated oil decreases from 10.5 mgNaCl/L to 5-6 mgNaCl/L without desalting current jump.

Key words: Tahe heavy crude oil, demulsification, desalting, mechanic impurities, commercial test

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