›› 2017, Vol. 48 ›› Issue (10): 60-65.

• 加工工艺 • 上一篇    下一篇

油田轻烃加氢生产低芳烃含量溶剂的两种工艺比较

王成1,姚劲1,乔恩1,唐明兴2   

  1. 1. 中国石油工程建设公司新疆设计分公司
    2. 中国科学院山西煤炭化学研究所
  • 收稿日期:2017-05-05 修回日期:2017-06-04 出版日期:2017-10-12 发布日期:2017-09-28
  • 通讯作者: 唐明兴 E-mail:mxtang@sxicc.ac.cn
  • 基金资助:
    国家自然科学基金青年基金

COMPARISON OF TWO PROCESSES FOR HYDROGENATION OF LIGHT HYDROCARBONS TO LOW AROMATIC SOLVENT

  • Received:2017-05-05 Revised:2017-06-04 Online:2017-10-12 Published:2017-09-28

摘要: 以硫质量分数为106 μg/g和25 μg/g的两种油田轻烃作为原料,比较两种加氢工艺的适用性。工艺Ⅰ采用CoMo/Al2O3加氢脱硫串联Ni/Al2O3加氢脱芳烃的组合工艺;工艺Ⅱ采用Ni/ZnO吸附脱硫串联Ni/Al2O3加氢脱芳烃的组合工艺。结果表明:对于工艺Ⅰ,两种原料在反应初期产品溴指数和芳烃含量均较低,但反应400 h和550 h后,产物芳烃质量分数大于0.1%;对于工艺Ⅱ,原料硫质量分数为25 μg/g时,在1 000 h内产品溴指数稳定在16 mgBr/(100 g)以下,芳烃质量分数稳定在0.09%以下。因此,工艺Ⅱ适合用于原料硫质量分数低于25 μg/g原料的深度加氢生产超低芳烃含量溶剂。

关键词: 加氢, 深度脱硫, 加氢脱芳烃, 植物抽提溶剂

Abstract: Two kinds of combined hydrogenation processes (CoMo/Al2O3 desulfurization+mid temperature ZnO + Ni/Al2O3 dearomatization process I and Ni/ZnO adsorption + Ni/Al2O3 process II) were compared to investigate which one is suitable for producing vegetable oil extraction solvent. The test feeds were two light hydrocarbons with S content of 106μg/g and 25μg/g, respectively. The results showed that the bromine indexes and the contents of aromatics are very low in initial reaction stage of process-I for the two feeds. But 400 h and 550 h later, the content of aromatics rises up and all exceeds 0.1%. For process-Ⅱ, when the sulfur content in feed is 25 μg/g, the bromine index of the product maintains below 16 mg Br/(100g), and the content of aromatics is less than 0.09%, indicating that processⅡis suitable for producing vegetable oil extraction solvent from the low s content feed.

Key words: hydrogenation, deep desulfurization, hydrodearomatization, vegetable oil extraction solvent