石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (11): 99-102.

• 分析与评定 • 上一篇    下一篇

能量色散X射线荧光光谱法测定汽油中铅、铁、锰含量

范艳璇,高萍,王轲   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2017-04-05 修回日期:2017-08-07 出版日期:2017-11-12 发布日期:2017-10-25
  • 通讯作者: 范艳璇 E-mail:fanyanxuan.ripp@sinopec.com
  • 基金资助:
     

SIMULTANEOUS DETERMINATION OF LEAD, IRON AND MANGANESE IN GASOLINE BY ENERGY-DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY

  1.  
  • Received:2017-04-05 Revised:2017-08-07 Online:2017-11-12 Published:2017-10-25
  • Supported by:
     

摘要: 利用能量色散X射线荧光光谱仪,建立了能量色散X射线荧光光谱法同时快速测定汽油中Pb,Fe,Mn含量的方法,并对方法进行了准确性和重复性考察。结果表明,Pb,Fe,Mn质量分数在0~100 μg/g范围内均具有良好的线性关系,检出限分别为0.06,0.4,0.09 μg/g,回收率均在91.7%~107.9%之间,相对标准偏差均小于3.0%。该方法可以同时快速测定汽油中的Pb,Fe,Mn元素含量。

关键词: 能量色散, X射线荧光光谱, 铅, 铁, 锰, 汽油, 分析方法

Abstract: AA method for determining elements of lead, iron and manganese in gasoline simultaneously by energy-dispersive X-ray fluorescence spectrometry (EDXRF) was developed. The precision of this method was inspected. The results show a great linear relationship in the ion concentration range from 0μg/g to 100μg/g. The detection limits for lead, iron and manganese are 0.06, 0.4 and 0.09 μg/g, respectively. The recovery rates are between 91.7% and 107.9%, and the relative standard deviation is less than 3%. This method for determination of Pb, Fe, Mn in gasoline simultaneously is more simple and fast.

Key words: energy-dispersive, X-ray flourescence, lead, iron, manganese, gasoline, test method

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