石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (5): 97-100.

• 油品与添加剂 • 上一篇    下一篇

采用DL/T285方法检测变压器油腐蚀性硫的试验研究

张绮,于会民,王会娟,马书杰   

  1. 中国石油兰州润滑油研究开发中心,中国石油润滑油重点实验室
  • 收稿日期:2016-11-09 修回日期:2017-01-03 出版日期:2017-05-12 发布日期:2017-04-25
  • 通讯作者: 张绮 E-mail:zhangqi_rhy@petrochina.com.cn
  • 基金资助:
     

DETECTION OF CORROSIVE SULFUR IN TRANSFORMER OIL BY DL/T285 TEST METHOD

    

  1.  
  • Received:2016-11-09 Revised:2017-01-03 Online:2017-05-12 Published:2017-04-25
  • Supported by:
     

摘要: 采用DL/T 285矿物绝缘油腐蚀性硫检测方法(裹绝缘纸的扁铜线法),考察精制深度不同的变压器油基础油及添加剂对变压器油潜在腐蚀性硫检测结果的影响。结果表明:精制深度不同、硫含量和芳烃含量不同的变压器油基础油中潜在腐蚀性硫检测的结果均为非腐蚀,试验扁铜线基本没有变色,绝缘纸上也没有硫化铜沉积物;抗氧剂对腐蚀性硫检测结果有一定的影响,即使添加金属钝化剂也未起到改善作用;在较高温度下,酚型抗氧剂会与试验扁铜线发生反应,使扁铜线表面出现蓝灰色或紫红色相间的条纹,对变压器油中腐蚀性硫判定的准确性产生严重的干扰。当对DL/T 285方法的分析结果存在疑点时,可采用SEM-EDX对试验扁铜线进行元素分析,判断是否含有硫元素。

关键词: 变压器油, 抗氧剂, DL/T 285方法, 腐蚀性硫

Abstract: The DL/T 285 method (the flat copper wrapped insulation paper method) was used to investigate the influence of the transformer base oils having different sulfur and aromatics content as well as common additives on potential corrosive sulfur measurement. The tests show that the detective results of potential corrosive sulfur for all base oils are non-corrosive, mainly no coloration changes of the copper wire and copper sulfide deposited on the insulating paper are found; however, the antioxidant addition has a certain effect on the test results, even if adding metal passivator; the phenolic antioxidant has an interference effect on the judgment for the results of corrosive sulfur by DL/T 285 method at higher temperature due to the reaction happens between additives and copper wire tested, leading to the appearance of blue and gray or purple and red stripes on the copper surface. When there is doubt about the analysis of the DL / T285 method, can use SEM-EDX elemental analysis to the flat copper wire used to determine if the corrosive element sulfur exists.

Key words: transformer oil, antioxidant additive, DL/T 285 method, corrosive sulphur

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