石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (8): 1-5.

• 加工工艺 •    下一篇

沿江炼油厂渣油加氢装置长周期运行及优化对策

邵志才,戴立顺,杨清河,聂红   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2017-01-19 修回日期:2017-01-13 出版日期:2017-08-12 发布日期:2017-07-19
  • 通讯作者: 邵志才 E-mail:shaozc.ripp@sinopec.com
  • 基金资助:
    中国石油化工股份有限公司合同项目

OPTIMIZING MEASURES FOR LONG PERIOD OPERATION OF VRDS UNITS IN REFINERIES ALONG THE YANGTZE RIVER

    

  1.  
  • Received:2017-01-19 Revised:2017-01-13 Online:2017-08-12 Published:2017-07-19
  • Contact: Zhi-Cai SHAO E-mail:shaozc.ripp@sinopec.com
  • Supported by:
     

摘要: 针对沿江炼油厂渣油加氢装置原料硫含量低、氮含量较高、金属Ni/V比高以及金属Fe和Ca含量高等特点,中国石化石油化工科学研究院提出了一系列解决方案:增设原油预脱钙措施,开发容垢能力更高的保护剂和残炭前身物加氢转化能力更强的催化剂,开发有针对性的催化剂级配技术,开发高效的反应物流分配技术,在部分炼油厂实施RICP工艺。工业应用结果表明,所开发的集成技术可充分发挥保护反应器的容垢能力和整体催化剂的活性,有利于沿江炼油厂渣油加氢装置的长周期运转。

关键词: 渣油加氢, 长周期, 运行, 优化, 解决方案

Abstract: The feeds of VRDS units in refineries along the Yangtze River are characterized by high nitrogen, low sulfur, high Ni/V ratio and large Fe,Ca content. A series of solutions were developed by Research Institute of Petroleum Processing and commercialized successfully. A crude decalcification facility was added and a guard catalyst with higher capability for FeS and CaS deposition was developed to solve the problem of high Ca content. Meanwhile a catalyst with higher HDCCR conversion for the low sulfur and high nitrogen content feed was applied. For realizing a longer cycle-length, a suitable catalyst grading technology, a high efficient flow distribution technology and the RICP process in some refineries were practiced. The results show that coke-make decreases dramatically, which is beneficial to the longer cycle-length.

Key words: residue hydrotreating, long cycle-length, operation, optimization, solution

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