石油炼制与化工 ›› 2017, Vol. 48 ›› Issue (8): 6-11.

• 加工工艺 • 上一篇    下一篇

流态化复合载体生物膜工艺处理高含盐炼油污水的研究

桑军强,赵锐,李本高,高峰,曹晓磊,马欣,秦冰   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2016-12-07 修回日期:2017-01-13 出版日期:2017-08-12 发布日期:2017-07-19
  • 通讯作者: 桑军强 E-mail:sangjq.ripp@sinopec.com
  • 基金资助:
    中国石油化工股份有限公司合同项目

APPLICATION OF FLUIDIZED CARRIER BIOFILM PROCESS IN REFINERY SALINE WASTERWATER TREATMENT

    

  1.  
  • Received:2016-12-07 Revised:2017-01-13 Online:2017-08-12 Published:2017-07-19
  • Supported by:
     

摘要: 流态化复合载体生物膜(FCBR)工艺使用中国石化石油化工科学研究院专利复合载体,可使生化反应器中的微生物浓度较常规流态化生物膜工艺增加近1倍,有效提高了生化处理能力和抗水质冲击能力,适用于处理高含盐炼油污水。某炼油厂的现场连续试验结果表明,在水力停留时间仅为厂内现有生化处理单元50%的情况下 (20 h),当进水COD质量浓度为185~620 mg/L、氨氮质量浓度为18~60 mg/L时,FCBR出水的COD质量浓度可降至150 mg/L以下,氨氮质量浓度不超过11 mg/L,悬浮物质量浓度基本不超过80 mg/L,处理效果明显优于现有生化单元,同时具有较强的抗水质冲击能力,可稳定满足后续催化氧化单元的要求,具有工业化应用前景。

关键词: 炼油污水, 生物膜, 流态化载体, COD, 氨氮, 悬浮物

Abstract: Fluidized carrier biofilm process (FCBR) loading with RIPP patented carriers was utilized to treat refinery saline wastewater. The results prove that FCBR could effectively remove influent chemical oxygen demand (COD), NH3-N and suspended solid from 185-620 mg/L, 18-60 mg/L and 50-520 mg/L to no more than 150 mg/L, 11 mg/L and 80 mg/L,respectively within a hydraulic retention time of 20 h. Comparing with the existing biological treatment system in oil refinery, the new FCBR has a higher efficiency within only a half of a hydraulic retention time. Under the actions of fluidized carrier, biomass concentration doubles that of conventional biofilm processes, and the FCBR effluent quality remains stable and meets the water quality requirement of the subsequent catalytic oxidation processes. Furthermore, the operation of FCBR is easy and low-cost, therefore it has a great potential for commercial application.

Key words: refining wastewater, biofilm, fluidized carrier, COD, NH3-N, suspended solid

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