石油炼制与化工 ›› 2018, Vol. 49 ›› Issue (4): 101-104.

• 分析与评定 • 上一篇    

植物还原法制备钯纳米单质的定量研究

贺媛媛,傅吉全   

  1. 北京服装学院材料科学与工程学院
  • 收稿日期:2017-09-11 修回日期:2017-12-28 出版日期:2018-04-12 发布日期:2018-04-26
  • 通讯作者: 贺媛媛 E-mail:771478484@qq.com
  • 基金资助:
     

QUANTITATIVE STUDY ON PREPARATION OF PALLADIUM NANOPARTICLES BY PLANT REDUCTION METHOD

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  • Received:2017-09-11 Revised:2017-12-28 Online:2018-04-12 Published:2018-04-26
  • Supported by:
     

摘要: 采用植物还原法,以PdCl2为钯前躯体,以银杏叶提取液为还原剂,将Pd2+离子从PdCl2溶液中还原出来,制备钯纳米单质。用电感耦合等离子体原子发射光谱 (ICP-AES)方法测定溶液中残留的Pd2+离子浓度,计算反应的还原率,完成对植物还原法制备纳米单质的定量研究。分别考察了钯前躯体PdCl2浓度和银杏叶干粉颗粒大小对Pd2+离子还原率的影响。结果表明:可以用ICP-AES方法对植物还原法进行定量研究;PdCl2浓度越大、银杏叶干粉颗粒越小,还原率越大。

关键词: 植物还原法, 钯纳米单质, 定量研究, 还原率

Abstract: Using PdCl2 as Pd particle precursor and Ginkgo biloba extract as reducing agent, nano Pd particles from PdCl2 solution were obtained by plant reduction method. The residual Pd2+ ion concentration in the reaction solution was measured by inductively coupled plasma atomic emission spectrometry (ICP-AES) to calculate quantitatively the reduction rate of the reaction. The effects of PdCl2 concentration and particle size of ginkgo leaf dry powder on the reduction rate of Pd2+ were investigated. The results showed that ICP-AES could be used to quantitatively study the plant reduction method, and that the higher the concentration of PdCl2, the smaller the dry powder particles, the higher the reduction rate.

Key words: plant reduction method, palladium nanoparticle, quantitative study, reduction rate

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