石油炼制与化工 ›› 2018, Vol. 49 ›› Issue (6): 33-36.

• 加工工艺 • 上一篇    下一篇

石蜡基柴油馏分的加氢异构化反应研究

许孝玲1,张景伟2,魏军2,王华2   

  1. 1.中国石油大学(北京)克拉玛依校区
    2.中国石油克拉玛依石化公司炼油化工研究院
  • 收稿日期:2017-10-30 修回日期:2017-11-19 出版日期:2018-06-12 发布日期:2018-06-20
  • 通讯作者: 许孝玲 E-mail:muzixxl@163.com
  • 基金资助:
     

HYDROISOMERIZATION OF PARAFFINIC BASED DIESEL FRACTION

    

  1.  
  • Received:2017-10-30 Revised:2017-11-19 Online:2018-06-12 Published:2018-06-20
  • Supported by:
     

摘要: 以石蜡基柴油馏分为原料,采用固定床加氢中试装置考察了加氢异构催化剂在不同工艺条件下的反应性能。结果表明:在一定范围内随着反应温度的提高,异构化反应和裂化反应程度持续增加;提高反应压力或空速,均不利于异构化和裂化反应的进行;反应压力提高,柴油的异构化反应活性降低,但可通过提高反应温度达到同样的降凝效果并且保持柴油馏分的收率变化不大。与催化脱蜡技术相比,在柴油馏分凝点接近时异构脱蜡所得柴油馏分的收率和十六烷指数明显较高。

关键词: 石蜡基, 柴油, 异构脱蜡, 催化脱蜡, 凝点

Abstract: Hydroisomerization of paraffinic base diesel fraction over a hydroisomerization catalyst was conducted in a fixed-bed reactor of pilot plant under different conditions. Results indicated that within a certain temperature range the hydroisomerization reaction and hydrocracking reaction are increased with increasing reaction temperature. While the hydroisomerization reaction and hydrocracking reaction is suppressed as the reaction pressure or space velocity increases. Although the hydroisomerization activity decreases with increasing reaction pressure, the same solidification point reduction can be reached by raising reaction temperature. While the yield of diesel fraction changes a little. Compared with catalytic dewaxing, the yields and cetane index of diesel are significantly higher in the case of hydrodewaxing when the solidification point of diesel is close.

Key words: paraffinic based, diesel, isodewaxing, catalytic dewaxing, solidification point

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