›› 2018, Vol. 49 ›› Issue (8): 66-69.

• 加工工艺 • 上一篇    下一篇

常一线油管式固定床选择性液相加氢生产喷气燃料的研究

崔小琴1,杨清贫2,郭朝晖2,屈叶青2   

  1. 1. 青海大学化工学院
    2. 湖南长岭石化科技开发有限公司
  • 收稿日期:2018-01-05 修回日期:2018-02-12 出版日期:2018-08-12 发布日期:2018-08-21
  • 通讯作者: 崔小琴 E-mail:cxq8916125@126.com

STUDY ON PRODUCTION OF JET FUEL BY FITS TECHNOLOGY OF THE FIRST ATMOSPHERIC SIDE-STREAM

Cui Xiaoqin,Yang Qingpin,Guo Zhaohui,Qu Yeqing   

  • Received:2018-01-05 Revised:2018-02-12 Online:2018-08-12 Published:2018-08-21
  • Contact: Cui Xiaoqin E-mail:cxq8916125@126.com

摘要: 本文分析了中石油青海油田格尔木炼厂生产航煤产品的优势和紧迫性;以格尔木炼厂常一线油为原料,进行了FITS加氢生产航煤的工艺研究,结果表明采用该技术可在较为缓和的条件下(反应压力3.0MPa、反应温度260℃、反应空速8.0h-1、氢油比10v/v)生产出满足GB6537-2006国家标准的军用和民用航煤产品;进一步提高反应苛刻(反应压力4.0MPa、反应温度300℃、反应空速8.0h-1、氢油比40v/v),可以生产出总硫含量小于10ppm的低硫清洁航煤产品;经过1000小时的稳定性试验,催化剂的活性保持平稳。以试验数据为基础设计的一套15万吨/年航煤FITS加氢工业装置的计算结果表明航煤FITS加氢装置在投资、占地和加工能耗等方面均低于现有同等规模加氢装置,具有良好的工业化前景。

关键词: 清洁喷气燃料, FITS加氢, 脱硫 , 催化活性, 长周期

Abstract: The clean jet fuel production by FITS technology using No.1 side-stream of atmospheric distillation of Geermu refinery as feed was studied. The effects of reaction pressure, temperature, space velocity and H2/oil ratio on FITS results were investigated, The test showed that the clean jet fuel with total sulfur content less than 10μg/g can be produced at conditions of 4.0 MPa, 300 ℃,LHSV 8.0 h-1,and hydrogen to oil ratio 40(v). The1000 hours continuous test indicated the excellent stability of the catalyst activity, the desulfurization rate keeps about 85%,mercapten removal about 87% and deacidification rate about 80%. It shows that the FITS process can realize the long - cycle production of clean jet fuel. The technical and economic assessment demonstrates that the FITS device is lower in construction investment, floor area and energy consumption than that of the same size trickle bed reactor, and has a good prospect of industrial application.

Key words: clean jet fuel, FITS hydrogenation, desulfurization, catalytic activity, long-cycle