石油炼制与化工 ›› 2018, Vol. 49 ›› Issue (9): 75-78.

• 催化剂 • 上一篇    下一篇

多产汽油的催化裂化催化剂LPC-70的工业应用

武兆东1,2,熊晓云3,马明亮,1高万山1   

  1. 1. 中国石油兰州石化分公司
    2.兰州大学化学化工学院
    3. 中国石油兰州化工研究中心
  • 收稿日期:2017-12-07 修回日期:2018-03-06 出版日期:2018-09-12 发布日期:2018-09-28
  • 通讯作者: 武兆东 E-mail:wuzhaod@petrochina.com.cn
  • 基金资助:
     

 

  1.  
  • Received:2017-12-07 Revised:2018-03-06 Online:2018-09-12 Published:2018-09-28
  • Contact: Zhao-Dong WU E-mail:wuzhaod@petrochina.com.cn
  • Supported by:
     

摘要: 多产汽油的催化裂化催化剂LPC-70含有富B酸多级孔基质材料APM-7,可有效提高重油转化能力,并提高汽油收率和液化气中的丙烯浓度。LPC-70催化剂在兰州石化3.0 Mt/a重油催化裂化装置应用结果表明,与空白标定相比,在原料劣质化和催化剂单耗降低0.2 kg/t的条件下,油浆产率下降0.71百分点,汽油收率增加2.53百分点,柴汽质量比由0.46下降至0.39,液化气中丙烯体积分数提高6.10百分点。

关键词: 催化裂化, 重油, 柴汽比, 丙烯, 催化剂

Abstract: To meet the refineries’ requirements for reducing diesel-to-gasoline ratio, Lanzhou Petrochemical Research Center, PetroChina, has successfully developed LPC-70 cracking catalyst for improving gasoline yield. In this catalyst, the hierarchical matrix material APM-7 with high content of Br?nsted acidities has been employed. It can improve gasoline yield and propylene content in LPG greatly as well as heavy oil conversion rate. Recent application of LPC-70 in Lanzhou Petrochemical Company has demonstrated that compared to the blank rating, with the lowing quality of feed oil and catalyst consumption, bottom yield decreased by 0.71%; gasoline yield increased by 2.53%; diesel-to-gasoline mass ratio of the unit decreased from 0.46 to 0.39 and the propylene content in liquid hydrocarbon increased by 6.10 percent point.

Key words: fluid catalytic cracking, heavy oil, diesel-to-gasoline ratio, propylene, catalyst

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