石油炼制与化工 ›› 2019, Vol. 50 ›› Issue (11): 11-15.

• 加工工艺 • 上一篇    下一篇

强电场渣油脱镍、钒实验研究

蒋兴家,王雪,崔新安   

  1. 中石化炼化工程(集团)股份有限公司洛阳技术研发中心
  • 收稿日期:2019-05-08 修回日期:2019-06-16 出版日期:2019-11-12 发布日期:2019-11-29
  • 通讯作者: 蒋兴家 E-mail:jiangxj.segr@sinopec.com
  • 基金资助:
     

EXPERIMENTAL STUDY OF REMOVING NICKEL AND VANADIUM FROM RESIDUE IN STRONG ELECTRIC FIELD

Jiang Xingjia,Wang Xue,Cui Xin'an   

  1. SINOPEC ENGINEERING GROUP LUOYANG R&D CENTER OF TECHNOLOGY
  • Received:2019-05-08 Revised:2019-06-16 Online:2019-11-12 Published:2019-11-29
  • Contact: Jiang Xingjia E-mail:jiangxj.segr@sinopec.com
  • Supported by:
     

摘要: 基于静电场对极性组分的极化作用,提出采用强电场的极化作用来打破渣油平衡体系,实现渣油中镍、钒的脱除。选用一种减压渣油,考察了温度(70~160 ℃)、停留时间(0.5~4 h)、电场强度(1 500~7 500 V/cm)和剂油质量比(0.5~6)对强电场作用下渣油中镍、钒脱除率的影响。结果表明:通过提高温度和剂油质量比来降低体系的黏度,有利于渣油中含镍、钒组分的移动和沉降;提高电场强度能够促进打破渣油的平衡体系而使渣油中含镍、钒极性组分聚结、沉降。在试验优选条件下(温度160 ℃、剂油质量比4、时间2 h、电场强度4 500 V/cm),镍、钒的脱除率分别达到了61.4%和70.4%,净化渣油收率达到88.2%。

关键词: 电场, 渣油, 镍,

Abstract: Based on the polarization effect of electrostatic field on polar components, the strong electric field was used to break the balance system of residue to remove nickel and vanadium. The effect of temperature (70-160℃),residence time (0.5-4h),solvent/residue mass ratio (0.5-6) and electric field intensity (1 500-7 500v/cm) on the removal ratio of nickel and vanadium were investigated. Results showed that increasing temperature and mass ratio of solvent/residue could reduce the viscosity of residue and facilitate movement and sedimentation of the nickel-containing and vanadium-containing components in the residue;increasing the electric field intensity was conducive to promote the agglomeration of polar components of nickel and vanadium compounds in the residue. The removal ratio of nickel and vanadium were 61.4% and 70.4%, respectively,under the optimum conditions of a temperature of 160 ℃,a solvent/residue mass ratio of 4,a residence time of 2 h and an electric field intensity of 4500 V/cm,and the yield of purified residue was 88.2%.

Key words: electric field, residue, nickel, vanadium

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