石油炼制与化工 ›› 2019, Vol. 50 ›› Issue (2): 68-72.

• 催化剂 • 上一篇    下一篇

FC-46多产化工原料型加氢裂化催化剂研制

刘昶1,黄娆2,郝文月1,曹均丰1,杜艳泽1,王凤来1,关明华1   

  1. 1. 中国石化大连(抚顺)石油化工研究院
    2. 西南石油大学
  • 收稿日期:2018-05-22 修回日期:2018-09-19 出版日期:2019-02-12 发布日期:2019-02-25
  • 通讯作者: 刘昶 E-mail:liuchang.fshy@sinopec.com
  • 基金资助:
     

DEVELOPMENT OF HYDROCRACKING CATALYST FOR HIGH YIELD CHEMICAL MATERIAL PRODUCTION

    

  1.  
  • Received:2018-05-22 Revised:2018-09-19 Online:2019-02-12 Published:2019-02-25
  • Supported by:
     

摘要: 选取适宜方法改性的分子筛和氧化铝作为载体组分,W-Ni作为加氢组分,采用UDRM技术制备出一种新型多产化工原料型FC-46催化剂。采用SEM、XPS等手段对催化剂进行了表征。以四氢萘和正十二烷为探针分子考察了FC-46催化剂的性能。与参比剂相比,FC-46催化剂作用下的四氢萘转化率提高0.7百分点,而正十二烷转化率降低2.1百分点。工业应用结果表明,FC-46催化剂活性略高于国外催化剂,产物的重石脑油选择性较国外催化剂作用下高0.7~1.0百分点,重石脑油芳烃潜含量比国外催化剂作用下高2.3~3.3百分点,喷气燃料烟点比国外催化剂作用下高2.5~3.7 mm,尾油BMCI值比国外催化剂作用下低1.9~2.8个单位。

关键词: 加氢裂化, 催化剂, 化工原料

Abstract: FC-46 is a new hydrocracking catalyst for maximally producing chemical materials. It is produced by UDRM technology using composite support of modified zeolite Y/macroporous alumina, W-Ni is used as a hydrogenation component. It was characterized by SEM and XPS techniques; the tetralin and dodecane were used to evaluate the performance of FC-46 catalyst. The results indicated that the conversion of tetralin increases by 0.7 percentage points, while dodecane conversion decreases by 2.1 percentage points using FC-46 compared with the reference catalyst. The industrial application of FC-46 catalyst showed that the activity of FC-46 catalyst is slightly higher than that of foreign catalyst: the heavy naphtha selectivity is 0.7-1.0 percentage points higher, the aromatic potential of heavy naphtha is 2.3-3.3 percentage points higher, the jet fuel smoke point is 2.5-3.7 mm higher, while UCO BMCI is 1.9-2.8 units lower than the reference catalyst.

Key words: hydrocracking, catalyst, chemical Material

中图分类号: