›› 2019, Vol. 50 ›› Issue (4): 7-11.

• 加工工艺 • 上一篇    下一篇

低酸耗硫酸法烷基化工艺技术中试研究

董明会   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2018-09-17 修回日期:2018-11-30 出版日期:2019-04-12 发布日期:2019-04-28
  • 通讯作者: 董明会 E-mail:dongminghui.ripp@sinopec.com

DEMONSTRATION TEST OF SULFURIC ACID ALKYLATION TECHNOLOGY WITH LOW ACID CONSUMPTION

  • Received:2018-09-17 Revised:2018-11-30 Online:2019-04-12 Published:2019-04-28

摘要: 中国石化石油化工科学研究院通过研制新型反应器、强化传质与分离过程等方法,研发出低酸耗硫酸法烷基化工艺技术,并在石家庄炼化分公司建成80 t/a硫酸烷基化中试装置。中试结果表明,烷基化油产品的研究法辛烷值可达96.5~97.0,终馏点小于197.5 ℃,满足烷基化油产品质量要求,是优质的汽油调合组分。中试稳定期间烷基化油标定酸耗为46.4 kg/t,酸耗较传统烷基化装置低。

关键词: 硫酸烷基化, 中试装置, 辛烷值, 低酸耗

Abstract: To meet the demand of domestic refineries for alkylate, an authorized low acid consumption sulfuric acid alkylation technology was developed by RIPP through the development of new reactors, enhanced mass transfer and separation processes. The demonstration plant test was conducted in an 80 t/a sulfuric acid alkylation unit built in SINOPEC Shijiazhuang Refining & Chemical Company. The test showed that the RON of the product was 96.5~97.0, the final boiling point was less than 197.5 °C. It meets the requirements of alkylation product and is a high-quality gasoline blending component. The acid consumption was determined to be 46.4 kg/t of alkylation product during the stable operation period, lower than the conventional technology.

Key words: sulfuric acid alkylation, demonstration unit, octane number, low acid consumption