石油炼制与化工 ›› 2019, Vol. 50 ›› Issue (8): 27-32.

• 催化剂 • 上一篇    下一篇

柴油超深度加氢脱硫催化剂级配技术的研究

葛泮珠,丁石,鞠雪艳,习远兵,李大东   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2018-10-09 修回日期:2019-03-03 出版日期:2019-08-12 发布日期:2019-08-27
  • 通讯作者: 葛泮珠 E-mail:gepzhu.ripp@sinopec.com
  • 基金资助:
     

RESEARCH ON CATALYST GRADING TECHNOLOGY FOR ULTRA LOW SULFUR DIESEL PRODUCTION

Ge Panzhu,Ding Shi,Ju Xueyan,Xi Yuanbing,Li Dadong   

  1.  
  • Received:2018-10-09 Revised:2019-03-03 Online:2019-08-12 Published:2019-08-27
  • Contact: Ge Panzhu E-mail:gepzhu.ripp@sinopec.com
  • Supported by:
     

摘要: 为更好发挥柴油超深度加氢脱硫(RTS)不同反应区域内不同类型催化剂的优势,在中型试验装置上考察了加氢反应活性高的 Ni-Mo-W型催化剂、直接脱硫反应活性高的Co-Mo型催化剂和具有轻微加氢改质活性的Ni-W型催化剂的不同级配方式对柴油超深度加氢脱硫反应的影响。结果表明:采用催化剂级配时与单独使用Ni-Mo-W催化剂时的超深度加氢脱硫效果相当;在第一反应器采用Ni-Mo-W型催化剂、第二反应器采用Ni-W型催化剂时,可有效降低加氢柴油产品的密度与多环芳烃含量;在第一反应器采用Ni-Mo-W型与Co-Mo型催化剂等体积比级配、第二反应器采用Co-Mo型催化剂的级配方案时,可有效降低柴油加氢反应的氢耗。

关键词: 超低硫柴油, 深度脱硫, 催化剂级配

Abstract: In order to make better use of catalysts in different reaction regions of diesel ultra deep hydrodesulfurization technology(RTS), in which two reactors in series were adopted,grading schemes for Ni-Mo-W type catalyst with high hydrogenation activity,Co-Mo type catalyst with high direct desulfurization activity,and Ni-W type catalyst with slight hydro-upgrading activity were compared in the pilot plant. The results showed that the effect of graded catalysts system on ultra-deep hydrodesulfurization was comparable to that of Ni-Mo-W catalyst alone. If Ni-Mo-W type catalyst was used in the first reactor and Ni-W type catalyst in the second reactor,the density and polycyclic aromatic hydrocarbon content of the product was effectively reduced. If the first reactor used Ni-Mo-W type and Co-Mo type catalyst in equal volume,and Co-Mo type catalyst was used in the second reactor,the hydrogen consumption could be effectively reduced.

Key words: ultra low diesel, deep desulfurization, catalyst grading technology

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