石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (4): 54-58.

• 加工工艺 • 上一篇    下一篇

催化裂化装置掺炼减四线油的工业实践

王慧   

  1. 中海油惠州石化有限公司
  • 收稿日期:2019-11-04 修回日期:2019-12-25 出版日期:2020-04-12 发布日期:2020-04-28
  • 通讯作者: 王慧 E-mail:wanghui68@cnooc.com.cn
  • 基金资助:
     

INDUSTRIAL PRACTICE OF BLENDING HVGO AS FCC UNIT FEED

    

  1. CNOOC Huizhou Petrochemical Company
  • Received:2019-11-04 Revised:2019-12-25 Online:2020-04-12 Published:2020-04-28
  • Supported by:
     

摘要: 为优化全厂产品结构,提高经济效益,中海油惠州石化有限公司在4.8 Mt/a催化裂化装置上进行了掺炼减四线油的工业实践。结果表明:减四线油掺炼比(w)达8.59%时,总液体收率降低0.77百分点,焦炭产率增加0.33百分点,能耗增加116.47 MJ/t;催化裂化干气的H2/CH4物质的量比略有增加,液化气和汽油中的烯烃体积分数分别增加0.21百分点和1.3百分点,汽油的密度(20 ℃)增加2.1 kg/m3,研究法辛烷值增加0.6个单位,芳烃体积分数增加1.9百分点,苯体积分数下降0.08百分点;平衡剂上的镍、钙质量分数分别增加388 μg/g和2 462 μg/g,并且随着掺炼减四线油时间的延长,平衡剂上的镍、钙含量仍持续上涨,需采取优化原油品种、加强原油脱盐、提高催化剂置换速率、加注多功能金属钝化剂等措施保证装置的长周期运行。

关键词: 催化裂化, MIP, 减四线油, 镍,

Abstract: An industrial practice of blending feedstock for FCC unit with vacuum gas oil from the fourth side-line has carried out in CNOOC Huizhou Petrochemical Company, which can optimize the product structure of the whole plant and improve economic benefits. The results showed that after blending ratio of the vacuum gas oil to 8.59%, the total liquid yield was decreased by 0.77 percentage point, the coke yield was increased by 0.33 percentage point, and the energy consumption was increased by 116.47 MJ/t; the molar ratio of H2/CH4 of catalytic dry gas was increased slightly, the olefin content of liquefied petroleum gas and gasoline were increased by 0.21 percentage point and 1.3 percentage points, respectively, the gasoline density(20 ℃) was increased by 2.1 kg/m3 and RON was increased by 0.6 unit, the aromatics content of gasoline was increased by 1.9 percentage points, and the benzene content of gasoline was decreased by 0.08 percentage point. The contents of Ni and Ca on equilibrium catalyst were increased by 388 μg/g and 2 462 μg/g, respectively, and would continue to increase over time, which would threaten the long-term operation of FCC unit. Measures should be taken to ensure long-term operation of FCC unit, such as optimizing crude oil varieties, intensifying crude oil desalination, increasing catalyst replacement speed, and adding multi-functional metal passivator.

Key words: FCC, MIP, HVGO, nickel, calcium

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