石油炼制与化工 ›› 2020, Vol. 51 ›› Issue (6): 47-51.

• 催化剂 • 上一篇    下一篇

微波法制备银镁共掺氧化锌复合光催化剂及其光催化性能研究

孙博,吴限,张金生,李丽华   

  1. 辽宁石油化工大学化学化工与环境学部
  • 收稿日期:2019-12-26 修回日期:2020-02-05 出版日期:2020-06-12 发布日期:2020-06-23
  • 通讯作者: 李丽华 E-mail:llh72@163.com
  • 基金资助:
     

MICROWAVE-ASSISTED SYNTHESIS OF SILVER-MAGNESIUM CO-DOPED ZINC OXIDE AND ITS PHOTOCATALYTIC PERFORMANCE

    

  1.  
  • Received:2019-12-26 Revised:2020-02-05 Online:2020-06-12 Published:2020-06-23
  • Supported by:
     

摘要: 采用环形聚焦单模微波辅助法(简称微波法)快速合成银镁共掺氧化锌复合光催化剂(简称复合光催化剂),并运用X射线衍射、扫描电子显微镜对其结构和形貌进行表征。将此复合光催化剂应用于光催化降解罗丹明B和含油污水,研究其光催化性能并探究光催化降解机理。结果表明:微波法合成的复合光催化剂具有良好的光催化性能,对含油污水的降解率优于商用二氧化钛;复合光催化剂重复使用4次后罗丹明B的降解率仍维持在92%以上,化学稳定性良好。。

关键词: 微波法, 氧化锌, 光催化剂, 含油污水

Abstract: A ring-focusing single-mode microwave synthesis method was used to rapidly synthesize a composite photocatalyst of silver-magnesium co-doped ZnO. XRD and SEM were used to characterize the structure and morphology of the synthesized photocatalyst. The photocatalytic degradation of Rhodamine B and oily wastewater by the photocatalyst was investigated. The performance and the mechanism of the reactions were explored. The results showed that the composite photocatalyst synthesized by microwave method had a good photocatalytic performance, and the degradation rate for oily wastewater was better than that of commercial titanium dioxide. After four cycles, the degradation rate of Rhodamine B was still above 92%, indicating that its chemical stability was good.

Key words: microwave method, zinc oxide, photocatalyst, oily wastewater

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