石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (11): 1-7.

• 加工工艺 •    下一篇

生产优质催化裂解原料的渣油深度加氢技术研究

邓中活,戴立顺,聂鑫鹏,方强,胡大为   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2021-01-21 修回日期:2021-03-06 出版日期:2021-11-12 发布日期:2021-10-29
  • 通讯作者: 邓中活 E-mail:dengzh.ripp@sinopec.com
  • 基金资助:
    中国石化科技项目渣油(劣质蜡油)深度加氢-催化裂解组合工艺研究

DEVELOPMENT OF RESIDUE DEEP HYDROTREATING TECHNOLOGY FOR PRODUCING HIGH QUALITY DEEP CATALYTIC CRACKING FEEDSTOCK

  • Received:2021-01-21 Revised:2021-03-06 Online:2021-11-12 Published:2021-10-29
  • Contact: Deng Zhonghuo E-mail:dengzh.ripp@sinopec.com

摘要: 以5种不同的渣油为原料,从催化剂开发、催化剂级配、工艺条件优化、原料适应性考察等角度深入研究并开发了渣油深度加氢技术。结果表明:新开发的渣油深度加氢系列催化剂活性显著高于常规催化剂;反应温度是影响加氢深度最关键的因素;在优化的催化剂级配方案和工艺条件下,渣油深度加氢技术不仅可以显著提高原料中杂原子的脱除率,提高生成油的氢含量,还可以实现多烃类定向转化产化学品;高硫、低氮常压渣油更适宜采用渣油深度加氢技术生产优质催化裂解原料。

关键词: 渣油深度加氢, 氢含量, 定向转化, 催化裂解原料

Abstract: Using five different kinds of residue as raw materials, the residue deep hydrotreating technology was developed from different perspectives such as catalyst development, catalyst grading technology development, process condition optimization, and raw material adaptability investigation. The investigation showed that the activity of the newly developed catalysts was significantly higher than that of the conventional catalysts, and the reaction temperature was the most critical factor affecting the hydrogenation depth. Under the optimized catalyst grading and process conditions, the residue deep hydrotreating technology achieved high-efficiency removal of heteroatoms and a significant increase in hydrogen content, and also realized the directional conversion of the dominant hydrocarbon which can produce more chemicals. The results also showed that the atmospheric residue with high sulfur and low nitrogen was suitable to be used as the feedstock of the residue deep hydrotreating technology to produce high quality catalytic cracking feedstock.

Key words: residue deep hydotreating, hydrogen content, directional conversion, deep catalytic cracking feedstock