石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (11): 19-23.

• 加工工艺 • 上一篇    下一篇

SINOALKY烷基化反应流出物精制技术的工业应用

杨跃进,刘健   

  1. 中国石化洛阳分公司
  • 收稿日期:2021-03-16 修回日期:2021-05-11 出版日期:2021-11-12 发布日期:2021-10-29
  • 通讯作者: 杨跃进 E-mail:yangyj.lysh@sinopec.com

INDUSTRIAL APPLICATION OF PURIFICATION TECHNOLOGY OF REACTION EFFLUENT FROM SINOALKY ALKYLATION PROCESS

  1. 1. SINOPEC Louyang Company
    2.
  • Received:2021-03-16 Revised:2021-05-11 Online:2021-11-12 Published:2021-10-29

摘要: 中国石化洛阳分公司200 kt/a烷基化装置采用SINOALKY硫酸法烷基化技术;与传统的硫酸法烷基化技术相比,SINOALKY硫酸法烷基化技术的反应流出物精制采用高效酸/烃聚结分离技术,取消了碱洗、水洗流程。介绍了SINOALKY烷基化反应流出物精制技术的原理、特点和优势,及其工业应用情况。2020年,中国石化洛阳分公司烷基化装置进行SINOALKY反应流出物精制技术的工业应用。结果表明,反应流出物进入分馏塔前,其硫质量分数在10 μg/g以下,烷基化油产品的质量合格。与传统的碱洗、水洗精制技术相比,采用SINOALKY精制技术后,装置能耗降低181.71 MJ/t,生产成本降低244.41万元/a,取得了良好的工业应用效果。

关键词: 烷基化, 酸烃分离, 聚结器, 碱洗

Abstract: The SINOALKY sulfuric acid alkylation technology was adopted in a 200 kt/a alkylation unit of SINOPEC Luoyang Company. Compared with the traditional sulfuric acid alkylation technology, the SINOALKY technology adopts high-efficiency acid-hydrocarbon coalescence and separation technology in the refining technology of the reaction effluent, and eliminates the process of alkaline washing and water washing, which is very different from the traditional technology. The principle, characteristics and advantages of the purification technology of SINOALKY alkylation reaction effluent are introduced, and its industrial application is studied. In 2020, the alkylation unit of SINOPEC Luoyang Company used SINOALKY reaction effluent purification technology. The results show that the sulfur content of the reaction product can be controlled below 10 μg/g before fractionation, and the quality of alkylate products are all qualified. Compared with traditional alkaline washing and water washing purification technology, the SINOALKY refining technology reduces the energy consumption by 181.71 MJ/t and the production cost by 2 444 100 CNY/a, and has achieved good industrial application effect.

Key words: alkylate, acid/hydrocarbon separation, coalescer, alkali washing