石油炼制与化工 ›› 2021, Vol. 52 ›› Issue (9): 63-68.

• 油品与添加剂 • 上一篇    下一篇

一种高温烷基二苯胺抗氧剂的合成与性能研究

徐瑞峰,罗意,李静,金理力,汤仲平   

  1. 中国石油兰州润滑油研究开发中心
  • 收稿日期:2020-12-28 修回日期:2021-05-27 出版日期:2021-09-12 发布日期:2021-08-30
  • 通讯作者: 徐瑞峰 E-mail:xuruifeng_rhy@petrochina.com.cn

SYNTHESIS AND PROPERTIES OF A HIGH TEMPERATURE ANTIOXIDANT ALKYL DIPHENYLAMINE

  • Received:2020-12-28 Revised:2021-05-27 Online:2021-09-12 Published:2021-08-30

摘要: 胺类抗氧剂具有良好的抗氧化性能,在控制油品黏度增长方面效果明显。在实验室合成了一种高温烷基二苯胺抗氧剂,采用旋转氧弹和PDSC方法对其在基础油中的抗氧化性能进行评价,并通过HTCBT、TEOST 33C、ROBO模拟氧化试验法、PDSC和热管等模拟评价手段考察该抗氧剂在全配方油品中的抗氧化性能。模拟结果显示,合成的抗氧剂具有较高的热稳定性,在TEOST 33C试验中表现出较优异的高温沉积物抑制能力。MS ⅢH台架试验结果表明,合成的抗氧剂在黏度增长控制方面表现优异。ROBO模拟氧化试验结果与台架试验结果具有较好的一致性,可以作为筛选抗氧剂的方法。台架和模拟试验结果表明,合成的抗氧剂是一种性能优异、可用在高端润滑油产品中的抗氧剂。

关键词: 胺类抗氧剂, 抗氧化性能, 程序ⅢH台架试验, ROBO模拟氧化试验法

Abstract: A high temperature antioxidant alkyl diphenylamine was synthesized in the laboratory. The anti-oxidation performance of the antioxidant in base oil was evaluated by rotating oxygen bomb and PDSC. The anti-oxidation performance of the antioxidant in full formula oil was investigated by HTCBT, TEOST 33C, ROBO, PDSC and heat pipe simulation evaluation methods. The simulation results show that the product has high thermal stability and excellent high temperature sediment inhibition ability in TEOST 33C. The results of Ⅲ H bench test show that the product has excellent performance in viscosity growth control. The ROBO process is consistent with the bench test results to a certain extent, which can be used as a method for screening antioxidants. The results of bench test and simulation test show that the antioxidant has excellent performance and can be used in high-grade lubricating oil products.

Key words: amine antioxidants, antioxidation property, MS Ⅲ H bench test, ROBO thermo-oxidation egine oil simulation test