石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (5): 63-68.

• 加工工艺 • 上一篇    下一篇

电场强化渣油脱金属试验研究

王雪1,2,蒋兴家1,2,崔新安1,2,申明周1,2,施振东1,2   

  1. 1.中石化炼化工程(集团)股份有限公司洛阳技术研发中心 2.中国石化石油化工设备防腐蚀研究中心
  • 收稿日期:2021-08-04 修回日期:2021-09-18 出版日期:2022-05-12 发布日期:2022-04-24
  • 通讯作者: 王雪 E-mail:wxforeverll@163.com
  • 基金资助:
    中国石油化工股份有限公司合同项目;中国石油化工股份有限公司合同项目

RESEARCH ON INTENSIFYING RESIDUE DEMETALIZATION BY ELECTRIC FIELD

  • Received:2021-08-04 Revised:2021-09-18 Online:2022-05-12 Published:2022-04-24

摘要: 渣油中的金属元素主要存在于胶质、沥青质等极性组分中。利用极性组分的带电特性,提出通过施加电场的方式来强化渣油脱金属反应,从而改善渣油性质,提高渣油综合利用价值。针对一种减压渣油,选取正庚烷为稀释溶剂,在电场作用下,考察了剂油质量比、电场强度及电场布置方式对渣油中Fe,Ca,Ni,V脱除的影响。结果表明,提高剂油质量比、提高电场强度、采用合理的电场布置方式均有利于渣油中金属的脱除。电场的强化作用促进了渣油中在自然沉降过程中较难析出、沉降的富含金属组分的脱除;在电场作用下,富含Ni、V的重质组分沿电场方向向罐壁移动、聚集、沉降,富含Fe、Ca的重质组分则向静电聚结罐底移动、沉降。

关键词: 渣油, 电场, 金属, 沥青质, 胶质

Abstract: The metal elements in residue mainly exist in polar components such as resin and asphaltene. Based on the electrification characteristics of the polar components, the method of applying electric field was proposed to enhance the demetalization of residue, so as to improve its properties and increase its comprehensive utilization value. The effects of mass ratio of solvent to oil, electric field intensity and electric field distribution on the removal of iron, calcium, nickel and vanadium in vacuum residue were investigated. The results show that increasing the solvent-oil ratio, increasing the electric field intensity and adopting reasonable electric field arrangement are beneficial to the removal of metal in residue. Under the action of electric field,the asphaltene rich in nickel and vanadium moves, accumulates and settles towards the wall of the tank, while the resins rich in iron and calcium moves and settles towards the electrode.

Key words: residue, electric field, metal, asphaltenes, resins