石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (6): 6-11.

• 加工工艺 • 上一篇    下一篇

催化裂化柴油加氢生产高密度喷气燃料过程研究

鞠雪艳,张锐,习远兵,任亮,赵杰   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2021-10-26 修回日期:2021-11-25 出版日期:2022-06-12 发布日期:2022-05-27
  • 通讯作者: 鞠雪艳 E-mail:juxueyan1223@163.com

STUDY ON THE PROCESS OF HIGH DENSITY JET FUEL PRODUCTION FROM FCC LCO

  • Received:2021-10-26 Revised:2021-11-25 Online:2022-06-12 Published:2022-05-27

摘要: 利用催化裂化柴油(LCO)密度较高且富含芳烃的性质特点,开展了以LCO为原料生产高密度喷气燃料的工艺研究。结果表明,以LCO为原料,采用高芳烃饱和活性的NiMoW/Al2O3加氢精制催化剂,在适当的工艺条件下进行超深度加氢饱和,可使LCO中芳烃质量分数降低至5%以下。进一步通过气相色谱-质谱(GC-MS)方法进行详细的烃类分析,可明确各烃类的分布规律并考察富集单环、二环及三环环烷烃的馏分,确定全馏分LCO加氢生产高密度喷气燃料时理想的终馏点为270~280 ℃,在此分馏温度下可得到冰点低于-47 ℃、密度(20 ℃)大于0.835 g/cm3 的高密度喷气燃料组分。

关键词: 催化裂化柴油, 超深度加氢, 高密度喷气燃料

Abstract: Based on the characteristics of high density and rich aromatics of FCC light cycle oil(LCO),the process technology of producing high-density jet fuel from the whole fraction of LCO was studied. The results show that the mass fraction of aromatics can be reduced to less than 5% by using NiMoW/Al2O3 hydrofining catalyst with high aromatics saturation activity through ultra-deep hydrogenation saturation under proper process conditions. Further detailed hydrocarbon analysis by gas chromatography-mass spectrometry (GC-MS) can clarify the distribution of hydrocarbons and investigate the fractions enriched with monocyclic,bicyclic and tricyclic cycloalkanes. The final boiling point of ideal fraction was 270 - 280 ℃ when the full fraction LCO was hydrogenated to produce high density jet fuel. Freezing point of high-density jet fuel component is lower than -47 ℃ and density(20 ℃)is greater than 0.835 g/cm3.

Key words: LCO, hydrotreating, high-density jet fuel