石油炼制与化工 ›› 2022, Vol. 53 ›› Issue (9): 27-32.

• 加工工艺 • 上一篇    下一篇

催化裂化原料烃类组成对低碳烯烃生成的影响

白旭辉,韩月阳,左严芬,王新,杜令印   

  1. 中国石化石油化工科学研究院
  • 收稿日期:2022-01-17 修回日期:2022-06-07 出版日期:2022-09-12 发布日期:2022-08-24
  • 通讯作者: 白旭辉 E-mail:baixuhui.ripp@sinopec.com

EFFECT OF HYDROCARBON COMPOSITION OF CATALYTIC CRACKING FEEDSTOCK ON THE PRODUCTION OF LIGHT OLEFINS

  • Received:2022-01-17 Revised:2022-06-07 Online:2022-09-12 Published:2022-08-24
  • Contact: Xu-Hui BAI E-mail:baixuhui.ripp@sinopec.com

摘要: 采用固定流化床反应装置,以加氢减压蜡油HVGO-1、HVGO-2、HVGO-3、HVGO-3轻馏分和HVGO-3重馏分为原料,考察了催化裂化原料烃类组成对低碳烯烃生成的影响。结果表明:与密度、氢含量相近的HVGO-1相比,HVGO-2中环烷烃含量高、芳烃含量低是低碳烯烃产率高的原因;HVGO-3、HVGO-3轻馏分和HVGO-3重馏分反应得到相同规律,即链烷烃、环烷烃和烷基苯是生产低碳烯烃和汽油的优势组分,其中,链烷烃和环烷烃是生成低碳烯烃的高价值组分,烷基苯是多产汽油和轻芳烃(BTX)的高潜能组分;HVGO-3轻馏分和HVGO-3重馏分在相同反应条件下,由于HVGO-3轻馏分中环烷基苯含量高,促使低碳烯烃前身物及低碳烯烃发生氢转移副反应,影响低碳烯烃生成;催化裂化原料加氢预处理通过控制加氢深度,实现多环芳烃超深度加氢转化为环烷烃,避免因加氢深度不够导致环烷基苯的生成,有利于提高低碳烯烃产率。

关键词: 加氢减压渣油, 催化裂化, 低碳烯烃

Abstract: A fixed fluidized bed reactor was used to study the effect of hydrocarbon components of catalytic cracking feedstock on the production of light olefins from the feedstock of HVGO-1, HVGO-2, HVGO-3, HVGO-3 light fraction and HVGO-3 heavy fraction. Compared with HVGO-1 with the similar density and hydrogen content, the higher cycloalkane content and lower aromatic content of HVGO-2 resulted in higher light olefins yield, and the same reaction rules were obtained for HVGO-3, HVGO-3 light fraction and HVGO-3 heavy fraction. Paraffins, naphthenes and monocyclic aromatics are the dominant components in the production of light olefins and gasoline. Among them, paraffins and naphthenes are the high value components in the production of light olefins, while alkylbenzenes are the high potential components in the production of gasoline and light aromatics (BTX). Under the same reaction conditions, the high content of cycloalkylbenzene in the HVGO-3 light fraction leads to the hydrogen transfer side reaction of light olefin precursors and light olefins, which affects the formation of light olefins. The hydrogenation pretreatment of FCC feedstock can improve the yield of light olefins by controlling the hydrogenation depth and realizing the conversion of polycyclic aromatic hydrocarbons to naphthenes, avoiding the formation of cycloalkylbenzene due to the lack of hydrogenation depth.

Key words: hydrogenated VGO, catalytic cracking, light olefins